Protein Information

Name CS 2
Synonyms CS 2; CSH 1; CSH1; Choriomammotropin; Placental lactogen; CSB; CSH 2; CSH2…

Compound Information

Name sulfur
CAS sulfur

Reference List

PubMed Abstract RScore(About this table)
19551772 Heldebrant DJ, Yonker CR, Jessop PG, Phan L: Reversible uptake of COS, CS2, and SO2: ionic liquids with O-alkylxanthate, O-alkylthiocarbonyl, and O-alkylsulfite anions. Chemistry. 2009 Aug 3;15(31):7619-27.

We now report the ability of such liquid blends to chemically bind and release other acid gases such as CS (2), COS, and SO (2) analogously to CO (2).
These systems bind with sulfur-containing acid gases to form colored ionic liquids with new O-alkylxanthate, O-alkylthiocarbonyl, and O-alkylsulfite anions.
1(0,0,0,1) Details
19425786 Neuefeind J, Fischer HE, Simonson JM, Idrissi A, Schops A, Honkimaki V: The structure of liquid carbon dioxide and carbon disulfide. J Chem Phys. 2009 May 7;130(17):174503.

We show that a 12-6-1 potential is completely adequate to describe the structure of CO (2); for CS (2) we find that the best 12-6-1 potential still slightly overestimates the height of the sulfur-sulfur pair-distribution function g (SS).
33(0,1,1,3) Details
20221535 Chen Y, Peng Y, Chen P, Zhao J, Liu L, Li Y, Chen S, Qu J: Insertion reactions of CS2, COS, and PhNCS at thiolate-bridged diiron centers. Dalton Trans. 2010 Mar 28;39(12):3020-5. Epub 2009 Dec 23.

Treatment of [Cp*Fe (mu (2)-SR)(3) FeCp*] (1a, R = Et; 1b, R = Me) with CS (2) obtains the insertion products [Cp*Fe (mu (2)-SR)(2)(mu-eta (2)-S (2) CSR) FeCp*] (2a, R = Et; 2b, R = Me) with the retained Fe (2) S (2) subunit in excellent yield. 2a and 2b represent the first examples for the CS (2) activation and incorporation at the diiron-SR bond. [Cp*Fe (mu (2)-SEt)(2)(mu-eta (2)-S (2)) FeCp*] (3) is prepared from COS and 1a through the decarbonylation and sulfur coupling reaction of COS resulting in the formation of S (2)(2-) ligand.
31(0,1,1,1) Details
20163106 Semeniuc RF, Reamer TJ, Blitz JP, Wheeler KA, Smith MD: Functionalized O-alkyldithiocarbonates: a new class of ligands designed for luminescent heterometallic materials. Inorg Chem. 2010 Mar 15;49(6):2624-9.

The new ligand 4-PyCH (2) OCS (2) Na, that combines two different donor groups in one molecule (a soft -CS (2)(-) group and a hard pyridine moiety), has been synthesized.
The ligand coordinates to a [(bipy) Re (CO)(3)](+) center in a monodentate fashion through one of its soft sulfur atoms, leaving the hard pyridine terminus free for further coordination chemistry.
1(0,0,0,1) Details
19826721 Darensbourg DJ, Andreatta JR, Jungman MJ, Reibenspies JH: Investigations into the coupling of cyclohexene oxide and carbon disulfide catalyzed by (salen) CrCl. Dalton Trans. 2009 Nov 7;(41):8891-9. Epub 2009 Aug 18.

The exchange of sulfur and oxygen atoms was observed in both the copolymer and cyclic products.
Density functional theory calculations were carried out on the possible cyclic materials from the coupling of cyclohexene oxide and CS (2), which revealed cyclohexylene trithiocarbonate to be the most stable cyclic species.
1(0,0,0,1) Details
20104312 Mas-Balleste R, Guijarro A, Gonzalez-Prieto R, Castillo O, Sanz Miguel PJ, Zamora F: S-S bond reactivity in metal-perthiocarboxylato compounds. Dalton Trans. 2010 Feb 14;39(6):1511-8. Epub 2009 Dec 10.

While M-percarboxylato species are elusive intermediates, their sulfur containing analogues are known in some cases.
Herein we report on the isolation of two new M-perthioacetato compounds: trans-[Pt (CH (3) CS (2) S)(2)] () and [Ni (CH (3) CSS)(CH (3) CS (2) S)] (), which have been fully characterized, including X-ray structures.
1(0,0,0,1) Details