| 19697947 |
Adams H, Bancroft MN, Morris MJ, Riddiough AE: Sequential construction of one, two, or three dithiolene ligands from alkynes and sulfur in dinuclear cyclopentadienyl molybdenum complexes. Inorg Chem. 2009 Oct 5;48(19):9557-66.
Further reaction of these complexes with 1 equiv of an alkyne R (3) C [triple bond] CR (4) (R (3) = R (4) = H, CO (2) Me; R (3) = H, R (4) = CO (2) Me) followed by oxidation with elemental sulfur produces the bis (dithiolene) complexes [Mo (2)(mu-S)(2)(SCR (1)=CR (2) S)(SCR (3)=CR (4) S) Cp (2)] (4a-d). |
31(0,1,1,1) |
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