| 19697947 |
Adams H, Bancroft MN, Morris MJ, Riddiough AE: Sequential construction of one, two, or three dithiolene ligands from alkynes and sulfur in dinuclear cyclopentadienyl molybdenum complexes. Inorg Chem. 2009 Oct 5;48(19):9557-66.
Reaction of 2 with an excess of an activated alkyne R (5) C [triple bond] CR (6) (R (5) = R (6) = CO (2) Me) and sulfur, or of 4 with the alkyne alone, affords good yields of the tris (dithiolene) complexes [Mo (2)(SCR (1)=CR (2) S)(SCR (3)=CR (4) S)(SCR (5)=CR (6) S) Cp (2)] (6a-e). |
31(0,1,1,1) |
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