| Name | PdCl 2 |
|---|---|
| Synonyms | GCPHLP; PDCL 2; PDCL2; Phosducin like 2; Phosducin like protein 2; Phosducin like 2s; Phosducin like protein 2s |
| Name | phosphine |
|---|---|
| CAS | phosphine |
| PubMed | Abstract | RScore(About this table) | |
|---|---|---|---|
| 19035585 | Chikkali SH, Gudat D, Lissner F, Niemeyer M, Schleid T, Nieger M: Template-controlled assembly of ditopic phosphines: a strategy for the generation of complexes of bidentate phosphines with different bite angles. Chemistry. 2009;15(2):482-91. A rational approach to the synthesis of heterobi- or -trimetallic complexes based upon self-assembly of a flexible ditopic -phosphine ligand with [(cod) PdCl (2)] and simple metal halides such as GaCl (3), BiCl (3), SnCl (4), or ZrCl (4) is described. |
81(1,1,1,1) | Details |
| 19388717 | Gauthier D, Beckendorf S, Gogsig TM, Lindhardt AT, Skrydstrup T: A ligand free and room temperature protocol for Pd-catalyzed Kumada-Corriu couplings of unactivated alkenyl phosphates. J Org Chem. 2009 May 1;74(9):3536-9. Kumada-Corriu cross-couplings of nonactivated cyclic and acyclic vinyl phosphates with aryl reagents afforded a series of 1,1-disubtituted alkenes in good yields for most cases when the reactions were performed at room temperature with the simple palladium salt, PdCl (2), without the presence of phosphine ligands. |
31(0,1,1,1) | Details |
| 20023958 | Bennett J, Doyle RJ, Lee HY, Lu D, Salem G, Speldewinde DJ, Tifan M, Willis AC: Synthesis of 1,3-azaphosphol-2-ones. Dalton Trans. 2010 Jan 7;(1):256-64. Epub 2009 Nov 10. The ligand (+/-)-pbap has also been complexed to palladium (II) via the reaction with Li (2)[PdCl (4)] in to give cis-[PdCl (2){(+/-)-pbap}(2)]. Reaction of secondary phosphine (+/-)-(2-aminophenyl) phenylphosphine, (+/-)-app, with PCl (5) in toluene gives the hydrochloride salt of the expected chlorophosphine (+/-)-(2-aminophenyl) chlorophenylphosphine, (+/-)-acpp.HCl, however, this is not the case with triphosgene. |
2(0,0,0,2) | Details |
| 15303177 | Montilla F, Galindo A, Rosa V, Aviles T: Effect of trimethylsilyl substitution on the chemical properties of triarylphosphines and their corresponding metal-complexes: solubilising effect in supercritical Dalton Trans. 2004 Aug 21;(16):2588-92. Epub 2004 Jul 21. The measurements of the J (P-Se) coupling constants of the corresponding synthesised selenides Se=P (Ar)(2)(Ar'), 2b,c and the DFT calculation of the energies of the phosphine lone-pair (HOMO) reveal insignificant influence on the electronic properties of the substituted phosphines when the trimethylsilyl group is attached to the aryl ring, in marked contrast to the strong electronic effect of the trifluoromethyl group. These triarylphosphine ligands P (Ar)(2)(Ar') reacted with (eta5-C (5) H (5)) Co (CO)(2), (eta5-C (5) H (5)) Co (2) or PdCl (2) to yield the new compounds (eta5-C (5) H (5)) Co (CO)[P (Ar)(2)(Ar')], 3b,d; (eta5-C (5) H (5)) CoI (2)[P (Ar)(2)(Ar')], 4b-e; and PdCl (2)[P (Ar)(2)(Ar')](2), 5b,c respectively. |
1(0,0,0,1) | Details |
| 15483709 | Green MJ, Cavell KJ, Edwards PG, Tooze RP, Skelton BW, White AH: Palladium (II) complexes of new OPN phosphine ligands and their application in homogeneously catalysed reactions of CO with alkenes or alkynes. Dalton Trans. 2004 Oct 21;(20):3251-60. Epub 2004 Aug 31. Ligands 1-3 form five membered P-N chelates which is confirmed for PdCl (2) complexes of and by X-ray crystallography. |
1(0,0,0,1) | Details |
| 15476383 | Lee HM, Zeng JY, Hu CH, Lee MT: A new tridentate pincer phosphine/n-heterocyclic carbene ligand: palladium complexes, their structures, and catalytic activities. Inorg Chem. 2004 Oct 18;43(21):6822-9. The complex, [Pd (PC (NHC) P) Cl] Cl (4), was prepared by the common route of silver carbene transfer reaction and a novel direct reaction between the ligand precursor, PC (NHC) P.HCl and PdCl (2) without the need of a base. |
1(0,0,0,1) | Details |
| 12737575 | Kuroboshi M, Waki Y, Tanaka H: Palladium-catalyzed tetrakis (dimethylamino) ethylene-promoted reductive coupling of aryl halides. J Org Chem. 2003 May 16;68(10):3938-42. The proper choice of palladium catalysts is essential for the reductive coupling; thus, PdCl (2)(PhCN)(2), PdCl (2)(MeCN)(2), Pd (hfacac)(2), Pd (2)(dba)(3), PdCl (2), and Pd (OAc)(2) were used successively for this reaction, but phosphine-ligated palladium catalysts such as Pd (PPh (3))(4), PdCl (2)(PPh (3))(2), and Pd (dppp) did not promote the reaction. |
0(0,0,0,0) | Details |