Protein Information

Name PCl 2
Synonyms M96; MTF 2; MTF2; Metal response element binding transcription factor 2; Metal regulatory transcription factor 2; Metal response element DNA binding protein M96; PCL 2; PCL2…

Compound Information

Name phosphine
CAS phosphine

Reference List

PubMed Abstract RScore(About this table)
17992279 Humphreys AS, Filipovska A, Berners-Price SJ, Koutsantonis GA, Skelton BW, White AH: Gold (I) chloride adducts of 1,3-bis (di-2-pyridylphosphino) propane: synthesis, structural studies and antitumour activity. Dalton Trans. 2007 Nov 21;(43):4943-50. Epub 2007 Sep 14.

The novel water soluble bidentate phosphine ligand 1,3-bis (di-2-pyridylphosphino) propane (d2pypp) has been synthesized by a convenient route involving treatment of 2-pyridyllithium with Cl (2) P (CH (2))(3) PCl (2) and isolation in crystalline form as the hydrochloride salt.
32(0,1,1,2) Details
19117419 Azouri M, Andrieu J, Picquet M, Cattey H: Synthesis of new cationic donor-stabilized phosphenium adducts and their unexpected P-substituent exchange reactions. Inorg Chem. 2009 Feb 2;48(3):1236-42.


When the reaction was performed with the 1,3-dimethylimidazolium-2-carboxylate 1a and PhPCl (2) in a 2:1 ratio, the phosphine 4a, bearing two imidazolium moieties, was obtained and led to 5a, after an anion exchange reaction with KPF (6), the latter being fully characterized by an X-ray structure analysis.
0(0,0,0,0) Details
12713309 Jiang XB, Minnaard AJ, Hessen B, Feringa BL, Duchateau AL, Andrien JG, Boogers JA, de Vries JG: Application of monodentate secondary phosphine oxides, a new class of chiral ligands, in Ir (i)-catalyzed asymmetric imine hydrogenation. Org Lett. 2003 May 1;5(9):1503-6.

Secondary phosphine oxides were prepared from R (1) PCl (2) and R (2) MgBr, followed by hydrolysis.
6(0,0,1,1) Details