Protein Information

Name PHIP
Synonyms IRS 1 PH domain binding protein PHIP; Ndrp; PHIP; PHIP protein; Pleckstrin homology domain interacting protein; WDR11; Ndrps; PHIP proteins…

Compound Information

Name phosphine
CAS phosphine

Reference List

PubMed Abstract RScore(About this table)
18682866 Lopez-Serrano J, Duckett SB, Dunne JP, Godard C, Whitwood AC: Palladium catalysed alkyne hydrogenation and oligomerisation: a parahydrogen based NMR investigation. Dalton Trans. 2008 Aug 28;(32):4270-81. Epub 2008 Jun 25.

The role phosphine ligands play in the palladium (ii)-bis-phosphine-hydride cation catalysed hydrogenation of diphenylacetylene is explored through a PHIP (parahydrogen induced polarization) NMR study.
81(1,1,1,1) Details
19319395 Godard C, Duckett SB, Polas S, Tooze R, Whitwood AC: An NMR study of cobalt-catalyzed hydroformylation using para-hydrogen induced polarisation. Dalton Trans. 2009 Apr 14;(14):2496-509. Epub 2009 Feb 16.

The relative ability of Co (eta3-C3H5)(CO) 2 (PR2R') to exchange phosphine for CO follows the trend PMe2Ph < PPh2Me < PCy3 < P (CH2Ph) 3 < PPh3.
Reactions of the allyl complexes with para-hydrogen (p-H2) lead to the observation of para-hydrogen induced polarisation (PHIP) in both liberated propene and propane.
3(0,0,0,3) Details
19072592 Atkinson KD, Cowley MJ, Duckett SB, Elliott PI, Green GG, Lopez-Serrano J, Khazal IG, Whitwood AC: Para-hydrogen induced polarization without incorporation of para-hydrogen into the analyte. Inorg Chem. 2009 Jan 19;48(2):663-70.


Parahydrogen induced polarization (PHIP) based on the hydride ligands of 2 and 3 is transferred efficiently to the 15N nuclei of the bound pyridine ligand by suitable insensitive-nuclei-enhanced-by-polarization-transfer (INEPT) based procedures.
1(0,0,0,1) Details