| 15510291 |
Otto S, Samuleev PV, Polyakov VA, Ryabov AD, Elding LI: Pseudo-rotation mechanism for fast olefin exchange and substitution processes at orthometalated C,N-complexes of platinum (II). Dalton Trans. 2004 Nov 7;(21):3662-8. Epub 2004 Oct 7.
Bridge splitting in chloroform of the orthometalated chloro-bridged complex [Pt (micro-Cl)(2-Me (2) NCH (2) C (6) H (4))](2)(1), with ethene, cyclooctene, allyl alcohol and phosphine according to 1+ 2L --> 2 [PtCl (2-Me (2) NCH (2) C (6) H (4))(L)], where L = C (2) H (4)(3a), C (8) H (14), (3b), CH (2) CHCH (2) OH (3c), and PPh (3)(4a and 4b) gives monomeric species with L coordinated trans or cis to aryl. |
31(0,1,1,1) |
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