| 17940652 |
Tanabe Y, Kajitani H, Iwasaki M, Ishii Y: Synthesis and reactivities of a bis (cyanamido)-capped triruthenium complex. Dalton Trans. 2007 Nov 7;(41):4701-7. Epub 2007 Aug 22.
Treatment of (2-) with 1 equiv. of HCl at room temperature leads to the protonation of one of the Ru-Ru edges to give the hydrido-bridged complex [(Cp*Ru) 3 (micro-H)(micro-NCN) 2], while the cationic side-on NCNH (2) complex [(Cp*Ru) 3 (micro-Cl)(micro (3)-NCN)(micro (3)-NCNH (2)-1kappaC,N:2kappaC:3kapp aN)] Cl (5) is obtained by the reaction of (2-) with an excess amount of HCl at -78 degrees C. |
1(0,0,0,1) |
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