Protein Information

Name PF6
Synonyms PF6; Projection protein PF6; RP4 776P7.2; SPAG17; sperm associated antigen 17; Projection protein PF6s; sperm associated antigen 17s

Compound Information

Name silica gel
CAS silica gel

Reference List

PubMed Abstract RScore(About this table)
15957033 Hagiwara H, Sugawara Y, Hoshi T, Suzuki T: Sustainable Mizoroki-Heck reaction in water: remarkably high activity of Pd (OAc) 2 immobilized on reversed phase silica gel with the aid of an ionic liquid. Chem Commun. 2005 Jun 21;(23):2942-4. Epub 2005 Jun 21.

Palladium acetate immobilized on reversed phase amorphous silica gel with the aid of an ionic liquid, [bmim] PF6, was highly efficient in the promotion of the Mizoroki-Heck reaction in pure water without a ligand up to the sixth re-use, in 95% average yield with TON and TOF 1,600,000 and 71,000 (h (-1)), respectively.
31(0,1,1,1) Details
16674081 Zhao X, Alper H, Yu Z: Stereoselective hydroxycarbonylation of vinyl bromides to alpha,beta-unsaturated carboxylic acids in the ionic liquid [BMIM] PF6. J Org Chem. 2006 May 12;71(10):3988-90.

The products are pure by proton NMR spectroscopic determination without purification by silica gel column chromatography or recrystallization.
2(0,0,0,2) Details
17996530 Liu Y, Sun X, Luo F, Chen J: The preparation of sol-gel materials doped with ionic liquids and trialkyl phosphine oxides for yttrium (III) uptake. Anal Chim Acta. 2007 Dec 5;604(2):107-13. Epub 2007 Oct 11.

The hydrophobic ionic liquid 1-octyl-3-methylimidazolium hexafluorophosphate (C8mim+ PF6 (-)) was used as solvent medium and pore templating material.
Ionic liquid was stably doped into the silica gel matrix providing a diffusion medium for Cyanex 923, and this will result in higher removal efficiencies and excellent stability for metal ions separation.
1(0,0,0,1) Details