17507753 |
Dorokhov AV, Chernyshov DY, Burlov AS, Garnovskii AD, Ivanova IS, Pyatova EN, Tsivadze AY, Aslanov LA, Chernyshev VV: Synchrotron powder diffraction in a systematic study of 4'-[2-(tosylamino) benzylideneamino]-2,3-benzo-15-crown-5 complexes. Acta Crystallogr B. 2007 Jun;63(Pt 3):402-10. Epub 2007 May 16.
In CuL (2) the four N atoms of two bidentate L ligands coordinate the Cu (II) ion in a distorted tetrahedral geometry with Cu-N distances of 1.98 (5)-2.05 (5) A, while two O atoms from two sulfoxide groups complete the distorted octahedral Cu coordination [Cu-O 2.64 (4), 2.74 (4) A]. |
35(0,1,1,5) |
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