Protein Information

Name Pr 3
Synonyms ACPA; p29; AGP 7; AGP7; Azurophil granule protein 7; C ANCA; C ANCA antigen; Leukocyte proteinase 3…

Compound Information

Name sulfoxide
CAS 5-[2-(octylsulfinyl)propyl]-1,3-benzodioxole

Reference List

PubMed Abstract RScore(About this table)
17451237 Scaffidi-Domianello YY, Nazarov AA, Haukka M, Galanski M, Keppler BK, Schneider J, Du P, Eisenberg R, Kukushkin VY: First example of the solid-state thermal cyclometalation of ligated benzophenone imine giving novel luminescent platinum (II) species. Inorg Chem. 2007 May 28;46(11):4469-82. Epub 2007 Apr 24.

The (benzophenone imine) platinum (II) compounds trans-[PtCl2 (Ph2C=NH)(RR'SO)] [R, R'=Me, Me (2); n-Pr, n-Pr (3); (CH2) 4 (4); Me, Ph (5); Me, p-MeC6H4 (6)] were prepared by the reaction of Ph2C=NH with K [PtCl3 (RR'SO)], obtained in situ from K2 [PtCl4] and the corresponding sulfoxide, giving 2-6 as well as cis-[PtCl2 (Ph2C=NH) 2] (1) as a minor product.
31(0,1,1,1) Details
19146434 Shaik N, Martinez A, Augustin I, Giovinazzo H, Varela-Ramirez A, Sanau M, Aguilera RJ, Contel M: Synthesis of Apoptosis-Inducing Iminophosphorane Organogold (III) Complexes and Study of Their Interactions with Biomolecular Targets. Inorg Chem. 2009 Feb 16;48(4):1577-87.


The presence of the P atom in the PR (3) fragment has been used as a "spectroscopic marker" to study the in vitro stability (and oxidation state) of the new organogold complexes in solvents like dimethyl sulfoxide and water.
2(0,0,0,2) Details
18031033 Lai SW, Chan QK, Zhu N, Che CM: cis-Dicyanoosmium (II) diimine complexes bearing phosphine or sulfoxide ligands: spectroscopic and luminescent studies. Inorg Chem. 2007 Dec 24;46(26):11003-16. Epub 2007 Nov 22.

The two PR3 (R = Ph, Me) or DMSO ligands are trans to each other with P/S-Os-P/S angles of approximately 177 degrees .
1(0,0,0,1) Details