11313553 |
Becker M, Jansen M: Zinc cyanamide, Zn (CN2). . Acta Crystallogr C. 2001 Apr;57(Pt 4):347-8. Single crystals of the title compound have been grown by annealing microcrystalline zinc cyanamide at 843 K in silver crucibles. Zn (CN (2)) crystallizes as colourless prisms. The crystal structure is composed of corner-linked ZnN (4/2) tetrahedra. Carbon and nitrogen form (CN (2))(2-) dumb-bells with the C atom on a twofold axis. Nitrogen is approximately trigonally planar, coordinated by two Zn atoms and one C atom. |
6(0,0,1,1) |