| 16458051 |
Mohamed HA, Ali SA, Ramadan RM: Spectroscopic and thermal studies of chromium (III), molybdenum (VI) and ruthenium (0) complexes of maleic hydrazide. Spectrochim Acta A Mol Biomol Spectrosc. 2006 Jul;64(4):913-7. Epub 2006 Feb 2.
Interaction of maleic hydrazide (LH (2)) with [Cr (CO)(6)] in air at atmospheric pressure resulted in the formation of the complex [(LH) Cr (mu-O)(2) Cr (LH)] (1). Reaction of LH (2) with [Mo (CO)(6)] in air also gave the complex [(LH (2)) O (2) Mo (mu-O)(2) MoO (2)(LH (2))] (2). Under the same conditions, the reaction of LH (2) with [Ru (3)(CO)(12)] resulted in the formation of the tricarbonyl complex [Ru (CO)(3)(LH (2))] (3). The complexes were characterized by elemental analysis, IR, and (1) H NMR spectroscopy. The thermal properties of the complexes were investigated by thermogravimetry technique. |
83(1,1,1,3) |