Protein Information

ID 4284
Name MTPA
Synonyms Long chain hydroxyacyl Coenzyme A dehydrogenase; GBP; TP alpha; TPalpha; HADH; HADHA; Hydroxyacyl CoA dehydrogenase/3 ketoacyl CoA; Hydroxyacyl Coenzyme A dehydrogenase/3 ketoacyl Coenzyme A…

Compound Information

ID 1404
Name phosphine
CAS phosphine

Reference

PubMed Abstract RScore(About this table)
15181630 Gati T, Simon A, Toth G, Magiera D, Moeller S, Duddeck H: Adducts of Rh2 [MTPA] 4 with some phosphine chalcogenides: nature of binding and ligand exchange. Magn Reson Chem. 2004 Jul;42(7):600-4.
Adducts of four phosphine chalcogenides with the chiral dirhodium complex ([Rh-Rh]) were investigated by variable-temperature 1H and 31P NMR spectroscopy in order to compare their properties as axial ligands. Whereas the selenide (1) and the sulfide (2) are strong ligands with electrostatic attraction and, in addition, a significant orbital (HOMO-LUMO) interaction, the phosphine oxide compounds (P=O) bind primarily via electrostatic attraction and are relatively weak donors. Moreover, the overall bond strength in these adducts depends on steric congestion around the P=O group.
31(0,1,1,1)