| Name | P b |
|---|---|
| Synonyms | P B; Salivary proline rich protein; Proline rich 3; Proline rich protein 3; PRL3; PB; PBII; PROL 3… |
| Name | phosphine |
|---|---|
| CAS | phosphine |
| PubMed | Abstract | RScore(About this table) | |
|---|---|---|---|
| 19918822 | Kim HW, Rhee YM: Dispersion-oriented soft interaction in a frustrated Lewis pair and the entropic encouragement effect in its formation. Chemistry. 2009 Dec 14;15(48):13348-55. This non-negligible direct P-B interaction, which is related also to the soft nature of the borane frontier orbital, is further supported by substantial spatial overlap between the frontier orbitals on the phosphine/borane fragments and their interaction energy estimations. |
32(0,1,1,2) | Details |
| 19449868 | Huynh K, Lough AJ, Forgeron MA, Bendle M, Soto AP, Wasylishen RE, Manners I: Synthesis and reactivity of phosphine-stabilized phosphoranimine cations, [R3P x PR'2=NSiMe3]+. J Am Chem Soc. 2009 Jun 10;131(22):7905-16. The salts [R (3) P x PR'(2)=NSiMe (3)] Br [R' = Me ([6](+)), OCH (2) CF (3) ([8](+)); R (3) P = Me (3) P (a), Et (3) P (b), (n) Bu (3) P (c), dmpm (d, dmpm = dimethylphosphinomethane), dmpe (e, dmpe = dimethylphosphinoethane)] were prepared from the direct reactions between BrMe (2) P=NSiMe (3) (5) and Br (CF (3) CH (2) O)(2) P=NSiMe (3) (7) and the corresponding tertiary phosphines R (3) P or the diphosphines Me (2) P (CH (2))(n) PMe (2) (n = 1, 2). |
1(0,0,0,1) | Details |
| 17896334 | Spies P, Frohlich R, Kehr G, Erker G, Grimme S: Structural importance of secondary interactions in molecules: origin of unconventional conformations of phosphine-borane adducts. Chemistry. 2008;14(1):333-43. The X-ray crystal structure analyses revealed close to eclipsed conformations for all members of this series with average dihedral angles theta (C-P-B-C) of 8.1 degrees (8 c), 12.3 degrees (8 b) and 20.3 degrees (8 a). |
1(0,0,0,1) | Details |
| 14753832 | Jaska CA, Lough AJ, Manners I: Linear hybrid aminoborane/phosphinoborane chains: synthesis, -hydride interactions, and thermolysis behavior. Inorg Chem. 2004 Feb 9;43(3):1090-9. The reaction of the lithiated phosphine-borane adducts Li [PPhR.BH (3)] or Li [CH (2)-PR (2).BH (3)] with Me (2) NH.BH (2) Cl afforded the hybrid linear species Me (2) NH-BH (2)-PPhR-BH (3) (1, R = Ph; 2, R = H) or Me (2) NH-BH (2)-CH (2)-PR (2)-BH (3) (3, R = Ph; 4, R = Me). Single-crystal X-ray diffraction studies on 1 and 3, the first for linear hybrid aminoborane/phosphinoborane adducts, confirmed the expected four-coordinate N-B-P-B and N-B-C-P-B frameworks. |
1(0,0,0,1) | Details |
| 19381415 | Nemeth B, Khater B, Veszpremi T, Guillemin JC: Synthesis, photoelectron spectroscopy and quantum chemical study of kinetically unstabilized phosphines complexed by borane. Dalton Trans. 2009 May 14;(18):3526-35. Epub 2009 Mar 17. Ethynyl- and allenylphosphine-boranes have been prepared by addition at low temperature of borane on the free phosphine. The photoelectron spectra can be easily described in the case of alpha,beta-unsaturated compounds by the change of the direct conjugation between the lone electron pair and the pi-bond in the free phosphines to hyperconjugation of the sigma (P-B) bond with the unsaturated moiety in the corresponding complexed derivatives. |
1(0,0,0,1) | Details |