| 16866490 |
Lopez-Serrano J, Duckett SB, Lledos A: Palladium-catalyzed hydrogenation: detection of palladium hydrides. J Am Chem Soc. 2006 Aug 2;128(30):9596-7.
Pd (PEt3) 2 (OTf) 2, acting as an in situ source of Pd (PEt3) 2, reacts with an alkyne and hydrogen via phosphine loss to form the detectable hydride-containing species Pd (PEt3) 2 (H)(CHPhCH2Ph), cis- and trans-Pd (PEt3) 2 (H)(CPh=CHPh), and Pd2 (PEt3) 3 (H)(CHPhCH2Ph) 2+, which map onto the reaction scheme predicted by density functional theory. |
31(0,1,1,1) |
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| 15732979 |
Oberbeckmann-Winter N, Morise X, Braunstein P, Welter R: Synthesis and structure of Pt (II) phosphonato-phosphine complexes and of a P,O-stabilized metal-metal-bonded Pt2Ag2 complex. Inorg Chem. 2005 Mar 7;44(5):1391-403.
The complexes 1, 2, 4, 5 x CH2Cl2, and (8 x OTf) 2 have been structurally characterized by single-crystal X-ray diffraction. |
1(0,0,0,1) |
Details |