Name | SPh 2 |
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Synonyms | ANK; ANK 1; ANK1; Ankyrin 1; Ankyrin R; Erythrocyte ankyrin; SPH 1; SPH 2… |
Name | phosphine |
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CAS | phosphine |
PubMed | Abstract | RScore(About this table) | |
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17378566 | Albrecht C, Schwieger S, Bruhn C, Wagner C, Kluge R, Schmidt H, Steinborn D: Alkylthio bridged 44 cve triangular platinum clusters: synthesis, oxidation, degradation, ligand substitution, and quantum chemical calculations. J Am Chem Soc. 2007 Apr 18;129(15):4551-66. Epub 2007 Mar 23. The analogous reaction of 2a-b with Ph2S2 gave SPh bridged dinuclear complexes trans-[{PtCl (L)}2 (mu-SPh) 2] (5), whereas the addition of Bn2S2 (Bn = benzyl) to 2a ended up in the formation of [{Pt (PPh3)}3 (mu3-S)(mu-SBn) 3] Cl (6). Phosphine ligands with a lower donor capability in clusters 4 proved to be subject to substitution by stronger donating monodentate phosphine ligands (L' = PMePh2, PMe2Ph, PBu3) yielding clusters [(PtL') 3 (mu-SR) 3] Cl (9). |
2(0,0,0,2) | Details |
19859603 | Canovese L, Visentin F, Chessa G, Santo C, Dolmella A: Substitution reactions between bis-chelate ligands in palladium (II) alkenyl complexes: an unusual way to form unstable trans-P complexes. Dalton Trans. 2009 Nov 21;(43):9475-85. Epub 2009 Sep 14. The substitution reactions between asymmetric bis-chelate ligands and alkenyl chloro derivatives of palladium (II) of the type [Pd (L-L')(Rx) Cl] (L-L' = 2-phenylsulfanylmethyl- (HN-SPh), 2-methyl-6-phenylsulfanylmethyl- (MeN-SPh), 2,2'-bipyridinyl (BiPy), Rx = -CCOOMe=CMeCOOMe (Ra), -CCOOEt=CMeCOOEt (Rb), -CCOOt-Bu=CMeCOOt-Bu (Rc), -(CCOOMe=CCOOMe)(2) Me (Rd)) with phosphoquinoline moieties (8-diphenylphosphanyl-quinoline (DPPQ), 8-diphenylphosphanyl-2-methyl-quinoline (DPPQ-Me)) usually leads to the formation of the stable geometrical isomer bearing these groups in the cis position thanks to the mutual trans influence of the alkenyl and phosphine groups. |
31(0,1,1,1) | Details |