Protein Information

Name SPh 2
Synonyms ANK; ANK 1; ANK1; Ankyrin 1; Ankyrin R; Erythrocyte ankyrin; SPH 1; SPH 2…

Compound Information

Name phosphine
CAS phosphine

Reference List

PubMed Abstract RScore(About this table)
17378566 Albrecht C, Schwieger S, Bruhn C, Wagner C, Kluge R, Schmidt H, Steinborn D: Alkylthio bridged 44 cve triangular platinum clusters: synthesis, oxidation, degradation, ligand substitution, and quantum chemical calculations. J Am Chem Soc. 2007 Apr 18;129(15):4551-66. Epub 2007 Mar 23.

The analogous reaction of 2a-b with Ph2S2 gave SPh bridged dinuclear complexes trans-[{PtCl (L)}2 (mu-SPh) 2] (5), whereas the addition of Bn2S2 (Bn = benzyl) to 2a ended up in the formation of [{Pt (PPh3)}3 (mu3-S)(mu-SBn) 3] Cl (6).
Phosphine ligands with a lower donor capability in clusters 4 proved to be subject to substitution by stronger donating monodentate phosphine ligands (L' = PMePh2, PMe2Ph, PBu3) yielding clusters [(PtL') 3 (mu-SR) 3] Cl (9).
2(0,0,0,2) Details
19859603 Canovese L, Visentin F, Chessa G, Santo C, Dolmella A: Substitution reactions between bis-chelate ligands in palladium (II) alkenyl complexes: an unusual way to form unstable trans-P complexes. Dalton Trans. 2009 Nov 21;(43):9475-85. Epub 2009 Sep 14.

The substitution reactions between asymmetric bis-chelate ligands and alkenyl chloro derivatives of palladium (II) of the type [Pd (L-L')(Rx) Cl] (L-L' = 2-phenylsulfanylmethyl-pyridine (HN-SPh), 2-methyl-6-phenylsulfanylmethyl-pyridine (MeN-SPh), 2,2'-bipyridinyl (BiPy), Rx = -CCOOMe=CMeCOOMe (Ra), -CCOOEt=CMeCOOEt (Rb), -CCOOt-Bu=CMeCOOt-Bu (Rc), -(CCOOMe=CCOOMe)(2) Me (Rd)) with phosphoquinoline moieties (8-diphenylphosphanyl-quinoline (DPPQ), 8-diphenylphosphanyl-2-methyl-quinoline (DPPQ-Me)) usually leads to the formation of the stable geometrical isomer bearing these groups in the cis position thanks to the mutual trans influence of the alkenyl and phosphine groups.
31(0,1,1,1) Details