Protein Information

Name Cl 2
Synonyms AMB11; MHC class I NK cell receptor; CD158E1; CD158E1/2; CD158E2; CL 11; CL 2; HLA BW4 specific inhibitory NK cell receptor…

Compound Information

Name phosphorus
CAS phosphorus

Reference List

PubMed Abstract RScore(About this table)
20162206 Fernandez-Anca D, Garcia-Seijo MI, Garcia-Fernandez ME: Tripodal polyphosphine ligands as inductors of chelate ring-opening processes in mononuclear palladium (II) and platinum (II) compounds. Dalton Trans. 2010 Mar 7;39(9):2327-36. Epub 2010 Jan 18.

The reaction of NP (3) (tris [2-(diphenylphosphino) ethyl] amine and PP (3) (tris [2-(diphenylphosphino) ethyl] phosphine) with the five-coordinate complexes [PdCl (NP (3))] Cl (1) and [MX (PP (3))] X [M = Pd: X = Cl (2), Br (3), I (4); M = Pt: X = Cl (5), Br (6), I (7)], respectively, followed by (31) P{(1) H}NMR when X = Cl, led to the formation of unprecedented four-coordinate halides in a 1 : 2 metal to ligand ratio, [M (AP (3))(2)] X (2) [A = N, M = Pd: X = Cl (8); A = P, M = Pd: X = Cl (9), Br (10), I (11); A = P, M = Pt: X = Cl (12), Br (13), I (14)], containing reactive dangling phosphorus.
31(0,1,1,1) Details
19453168 Chandrasekhar V, Murugesapandian B: Phosphorus-supported ligands for the assembly of multimetal architectures. Acc Chem Res. 2009 Aug 18;42(8):1047-62.

In this Account, we describe the utility of inorganic heterocyclic rings such as cyclophosphazenes and carbophosphazenes as well as acyclic phosphorus-containing compounds such as (S) PCl (3), RP (O) Cl (2), and R (2) P (O) Cl for building such multisite coordination platforms.
6(0,0,1,1) Details
19913918 Das S, Sinha S, Britto R, Somasundaram K, Samuelson AG: Cytotoxicity of half sandwich ruthenium (II) complexes with strong hydrogen bond acceptor ligands and their mechanism of action. J Inorg Biochem. 2010 Feb;104(2):93-104. Epub 2009 Oct 8.

In cationic complexes, X, Y is either a eta (2) phosphorus ligand such as 1,1-bis (diphenylphosphino) methane (DPPM) and 1,2-bis (diphenylphosphino) ethane (DPPE) or partially oxidized ligands such as 1,2-bis (diphenylphosphino) methane monooxide (DPPMO) and 1,2-bis (diphenylphosphino) ethane monooxide (DPPEO) which are strong hydrogen bond acceptors.
Complexes with DPPM and DPPMO ligands ([(eta (6)-cymene) Ru (eta (2)-DPPM) Cl] PF (6) (R2), [(eta (6)-cymene) Ru (eta (2)-DPPMO) Cl] PF (6) (R3), [(eta (6)-cymene) Ru (eta (1)-DPPM) Cl (2)] (R5) and [(eta (6)-cymene) Ru (eta (1)-DPPMO) Cl (2)] (R6) show good cytotoxicity.
1(0,0,0,1) Details
19921847 Zhang J, Pattacini R, Braunstein P: Tridentate assembling ligands based on oxazoline and phosphorus donors in dinuclear Pd (I)-Pd (I) complexes. Inorg Chem. 2009 Dec 21;48(24):11954-62.

In contrast, the reaction between [Pd (2)(NCMe)(6)](BF (4))(2) and NOPON (Me2) in the presence of LiCl afforded the mononuclear cationic complex [Pd (NOPON (Me2)-N,P,N) Cl](BF (4)) (3), which is also obtained by halide abstraction from [Pd (NOPON (Me2)-N,P) Cl (2)] with NaBF (4).
1(0,0,0,1) Details
19317408 Ganesamoorthy C, Balakrishna MS, Mague JT: Group 11 metal chemistry of a tetradentate ligand, phenylene-1,4-diaminotetra (phosphonite), p-C6H4 [N{P (OC6H4OMe-o) 2}2] 2. Inorg Chem. 2009 Apr 20;48(8):3768-82.

Complex 14 undergoes moisture-assisted P-N bond cleavage in the presence of PhN{P (OC (6) H (4) OMe-o)(2)}(2) to give [p-NH (2) C (6) H (4) N{P (OC (6) H (4) OMe-o)(2)}(2) Au (2) Cl (2)] (17) and [PhN{P (OC (6) H (4) OMe-o)(2)}(2) Au (2) Cl (2)].
The o-methoxyphenoxy substituents on phosphorus in complexes 5 and 7 adopt approximately parallel planar conformations and contain lattice solvents.
1(0,0,0,1) Details