| 12562177 |
Gandhi T, Nethaji M, Jagirdar BR: Novel double insertion of carbon disulfide into two Ru-H bonds of [(dppm)(2) Ru (H)(2)] (dppm = Ph (2) PCH (2) PPh (2)): synthesis and crystal structure of a methanedithiolate complex. Inorg Chem. 2003 Feb 10;42(3):667-9.
Addition of excess carbon disulfide to cis/trans-[(dppm)(2) Ru (H)(2)] results in the methanedithiolate complex [(dppm)(2) Ru (eta (2)-S (2) CH (2))] 4 via the intermediacy of cis-[(dppm)(2) Ru (H)(SC (S) H)] 2. The X-ray crystal structure of this species has been determined. |
31(0,1,1,1) |