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Khatri OP, Adachi K, Murase K, Okazaki K, Torimoto T, Tanaka N, Kuwabata S, Sugimura H: Self-assembly of ionic liquid (BMI-PF6)-stabilized gold nanoparticles on a silicon surface: chemical and structural aspects. Langmuir. 2008 Aug 5;24(15):7785-92. Epub 2008 Jun 24.
Ultrafine monodisperse gold nanoparticles (AuNPs) were synthesized by an elegant sputtering of gold onto 1- n-butyl-3-methylimidazolium hexafluorophosphate (BMI-PF (6)) ionic liquid. It was found that the BMI-PF (6) supramolecular aggregates were loosely coordinated to the gold nanoparticles and were replaceable with thiol molecules. The self-assembly of BMI-PF (6)-stabilized AuNPs onto a (3-mercaptopropyl) trimethoxysilane (MPS)-functionalized silicon surface in 2D arrays, followed by dodecanethiol (DDT) treatment, have been demonstrated using X-ray photoelectron spectroscopy, field emission scanning electron microscopy, and contact angle measurements. DDT treatment of tethered AuNPs revealed two types of interactions between AuNPs and the MPS-functionalized surface: (a) AuNPs anchor through Au-S chemisorption linkage resulting in strong immobilization and (b) some of the AuNPs are supported by physisorption, driven by BMI-PF (6). The attachment of these particles remains unchanged with sonication. The replacement of BMI-PF (6) aggregates from physisorbed AuNPs with DDT molecules advances the dilution of their interaction with the MPS-functionalized surface, and they subsequently detach from the silicon surface. The present finding is promising for the immobilization of ionic liquid-stabilized nanoparticles, which is very desirable for electronic and catalytic device fabrication. Additionally, these environmentally friendly AuNPs are expected to replace conventional citrate-stabilized AuNPs. |
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