| 19650627 |
Norton DM, Mitchell EA, Botros NR, Jessop PG, Baird MC: A superior precursor for palladium (0)-based cross-coupling and other catalytic reactions. J Org Chem. 2009 Sep 4;74(17):6674-80.
The easily synthesized, easily handled compound Pd (eta (3)-1-PhC (3) H (4))(eta (5)-C (5) H (5)) (II) reacts readily with mono- and bidentate tertiary phosphines to produce the corresponding bis-phosphine palladium (0) complexes in good yields; II is thus an excellent precursor, perhaps the most efficacious and reliable available, for the synthesis of palladium (0) cross-coupling catalysts. |
31(0,1,1,1) |