Protein Information

Name Cl 2
Synonyms AMB11; MHC class I NK cell receptor; CD158E1; CD158E1/2; CD158E2; CL 11; CL 2; HLA BW4 specific inhibitory NK cell receptor…

Compound Information

Name sulfur
CAS sulfur

Reference List

PubMed Abstract RScore(About this table)
19746999 Han YG, Xu C, Duan T, Wu FH, Zhang QF, Leung WH: Heterometallic aggregates of copper (I) with metalloligand Sn (edt) 2 (edt = ethane-1,2-dithiolate): syntheses and structures of [Sn (edt) 2Cl (mu-I)(mu3-I)(CuPPh3) 3], [Sn (edt) 2 (mu-Br) 2 (mu3-Br) 2 (CuPPh3) 4], and [{Sn (edt) 2}3 (mu-OH) 3Cu5 (PPh3) 8][PF6] 2. Inorg Chem. 2009 Sep 21;48(18):8796-802.

The treatment of a slurry of an equimolar mixture of [Sn (edt)(2)] (edt = ethane-1,2- dithiolate) and [Et (4) N] Cl.xH (2) O with CuI in the presence of PPh (3) gave a tetranuclear compound, [Sn (edt)(2) Cl (mu-I)(mu (3)-I)(CuPPh (3))(3)] (1), which consists of a rectangular-pyramidal [Sn (edt)(2) Cl](-) moiety ligated by three [Cu (PPh (3))](+) fragments via the sulfur atoms of the edt (2-) ligands.
Reaction of [Sn (edt)(2)] with [Cu (MeCN)(4)][PF (6)] and PPh (3) in a mixed MeCN/CH (2) Cl (2) solution yielded a novel octanuclear compound, [{Sn (edt)(2)}(3)(mu-OH)(3) Cu (5)(PPh (3))(8)][PF (6)](2) (3), which may be described as a triangular [{Sn (edt)(2)}(3)(mu-OH)(3)](3-) core chelated by three [Cu (PPh (3))(2)](+) species and capped by two [Cu (PPh (3))](+) species.
3(0,0,0,3) Details
19432428 Milsmann C, Bothe E, Bill E, Weyhermuller T, Wieghardt K: Octahedral Monodithiolene Complexes of Cobalt (III) and Chromium (III). Inorg Chem. 2009 May 11.

Comparison with the corresponding o-benzosemiquinonate (1-) complexes shows that the S,S'-coordinated benzene-1,2-dithiolate (1-) radical is a sulfur centered radical whereas its oxygen containing analogue carries approximately 65% of the spin density on the six-membered ring.
The reaction of [M (tren) Cl (2)] Cl (M = Co (III), Cr (III)) with benzene-1,2-dithiol, H (2)(bdt), and 3,6-bis (trimethylsilyl) benzene-1,2-dithiol, H (2)(tmsdt), in a water/methanol mixture in the presence of potassium tert-butoxide produced green crystals of [M (tren)(bdt)](PF (6))(1/2)(Cl)(1/2).H (2) O (1 (PF (6))(1/2)(Cl)(1/2).H (2) O, M = Co; 2 (PF (6))(1/2)(Cl)(1/2).H (2) O, M = Cr) and [M (tren)(tmsdt)](PF (6))(1/2)(Cl)(1/2).H (2) O (1a (PF (6))(1/2)(Cl)(1/2).H (2) O, M = Co; 2a (PF (6))(1/2)(Cl)(1/2).H (2) O, M = Cr), respectively, upon addition of KPF (6).
2(0,0,0,2) Details
20104915 Tuncaboylu DC, Okay O: Hierarchically Macroporous Cryogels of Polyisobutylene and Silica Nanoparticles. Langmuir. 2010 Jan 28.

The gels were prepared by cross-linking of butyl rubber in cyclohexane containing silica nanoparticles using sulfur monochloride (S (2) Cl (2)) as a cross-linking agent.
6(0,0,1,1) Details
19449357 Decken A, Knapp C, Nikiforov GB, Passmore J, Rautiainen JM, Wang X, Zeng X: Silver (I) complexes of the weakly coordinating solvents SO (2) and CH (2) Cl (2): crystal structures, bonding, and energetics of [Ag (OSO)][Al{OC (CF (3))(3)}(4)], [Ag (OSO)(2/2)][SbF (6)], and [Ag (CH (2) Cl (2))(2)][SbF (6)]. Chemistry. 2009 Jun 22;15(26):6504-17.

Pushing the limits of coordination chemistry: The most weakly coordinated silver complexes of the very weakly coordinating solvents dichloromethane and liquid sulfur dioxide were prepared.
5(0,0,0,5) Details
20043673 Ohmae T, Nishinaga T, Wu M, Iyoda M: Cyclic tetrathiophenes planarized by silicon and sulfur bridges bearing antiaromatic cyclooctatetraene core: syntheses, structures, and properties. J Am Chem Soc. 2010 Jan 27;132(3):1066-74.

Furthermore the colors of the solutions of 1 (lambda (max) = 483 nm), 2b (lambda (max) = 618 nm), and 3b (lambda (max) = 575 nm) were orange, purple, and red in CH (2) Cl (2), respectively, indicating that the HOMO-LUMO gaps of 1-3 become increasingly narrow with increasing planarity of the COT ring.
1(0,0,0,1) Details
19789783 Bowmaker GA, Chaichit N, Hanna JV, Pakawatchai C, Skelton BW, White AH: Spectroscopy and structures of two complete families, one mononuclear, the other binuclear, of 1 : 2 CuX : dptu stoichiometry (X = Cl, Br, I; 'dptu' = N,N'-diphenylthiourea). Dalton Trans. 2009 Oct 21;(39):8308-16. Epub 2009 Aug 13.

A (solvated) sulfate salt is found to be of the form [Cu (dptu)(2)](2)(SO (4)), providing a novel example of a copper (i) atom being (quasi-) linearly coordinated by the pair of unidentate (dptu) sulfur ligands, Cu-S 2.1770 (5), 2.1811 (5) A, S-Cu-S 162.18 (2) degrees .
The broadline static (65) Cu NMR spectra of [Cl (2) Cu (2)(dptu)(4)].2CH (3) CN and [X (2) Cu (2)(dptu)(4)] (X = Br, I) have been recorded at 9.4 and 7.05 T, and the spectra have been analysed to yield the (65) Cu nuclear quadrupole coupling and chemical shift parameters.
1(0,0,0,1) Details
19575350 Wright RJ, Lim C, Tilley TD: Diiron proton reduction catalysts possessing electron-rich and electron-poor naphthalene-1,8-dithiolate ligands. Chemistry. 2009 Aug 24;15(34):8518-25.


Cyclic voltammetry (CH (2) Cl (2)/nBu (4) PF (6)) revealed two one-electron reductions, at potentials more positive than those for the related [Fe (2)(CO)(6)(S (CH (2))(3) S)] (1), and one one-electron oxidation.
1(0,0,0,1) Details
19924962 Gendel Y, Levi N, Lahav O: H2S (g) removal using a modified, low-ph liquid redox sulfur recovery (LRSR) process with electrochemical regeneration of the Fe catalyst couple. Environ Sci Technol. 2009 Nov 1;43(21):8315-9.

Fe (II) was oxidized in a flow-through electrolytic cell by Cl (2 (aq)) formed on a Ti/RuO (2) anode. pH 1.0 was applied to retard the potential precipitation of predominantly jarosite group Fe (III) species.
1(0,0,0,1) Details
20018556 Krishnan S, Laly K, Prathapachandra Kurup MR: Synthesis and spectral investigations of Mn (II) complexes of pentadentate bis (thiosemicarbazones). Spectrochim Acta A Mol Biomol Spectrosc. 2010 Feb;75(2):585-8. Epub 2009 Nov 18.

Five Mn (II) complexes of bis (thiosemicarbazones) which are represented as [Mn (H (2) Ac4Ph) Cl (2)] (1), [Mn (Ac4Ph) H (2) O] (2), [Mn (H (2) Ac4Cy) Cl (2)].H (2) O (3), [Mn (H (2) Ac4Et) Cl (2)].3H (2) O (4) and [Mn (H (2) Ac4Et)(OAc)(2)].3H (2) O (5) have been synthesized and characterized by elemental analyses, electronic, infrared and EPR spectral techniques.
In all the complexes except [Mn (Ac4Ph) H (2) O], the ligands act as pentadentate neutral molecules and coordinate to Mn (II) ion through two thione sulfur atoms, two azomethine nitrogens and the pyridine nitrogen, suggesting a heptacoordination.
1(0,0,0,1) Details
19572498 Milsmann C, Patra GK, Bill E, Weyhermuller T, DeBeer George S, Wieghardt K: Octahedral monodithiolene complexes of iron: characterization of S,S'-coordinated dithiolate (1-) pi radical monoanions: a spectroscopic and density functional theoretical investigation. Inorg Chem. 2009 Aug 3;48(15):7430-45.

The reaction of cis-[Fe (III)(cyclam) Cl (2)] Cl with 1 equiv of sodium N-diethyldithiocarbamate, toluene-3,4-dithiolate, and maleonitriledithiolate in methanol in the presence of triethylamine afforded the cations [Fe (III)(cyclam)(Et (2) dtc)](2+) (1), [Fe (III)(cyclam)(tdt)](+) (2), and [Fe (III)(cyclam)(mnt)](+) (3), which were isolated as triflate, hexafluorophosphate, and tetrafluoroborate salt, respectively, using sodium triflate, potassium hexafluorophosphate, or sodium tetrafluoroborate as the source for the counteranion.
The analysis of the sulfur K pre-edge transitions reveals significant multiplet effects in the spectra of 2 and 2 (ox), which provide rare experimental evidence for a singlet diradical description for 2 (ox).
1(0,0,0,1) Details
19893229 Dols TS, Spaniol TP, Okuda J: Titanium complexes with sulfur-linked bis (phenolate) ligands. . Acta Crystallogr C. 2009 Nov;65(Pt 11):m443-6. Epub 2009 Oct 24.

High-quality crystals of two bis (phenolate) titanium complexes, namely dichlorido{4,4'-dimethyl-2,2'-[cyclohexane-1,2-diylbis (sulfanediyl)] diphen olato}titanium (IV), [Ti (C (20) H (22) O (2) S (2)) Cl (2)], (I), and dichlorido{2,2'-[cyclohexane-1,2-diylbis (sulfanediyl)] diphenolato}titanium (IV), [Ti (C (18) H (18) O (2) S (2)) Cl (2)], (II), were obtained by reactive crystallization.
1(0,0,0,1) Details
20301142 Valore A, Cariati E, Dragonetti C, Righetto S, Roberto D, Ugo R, De Angelis F, Fantacci S, Sgamellotti A, Macchioni A, Zuccaccia D: Cyclometalated Ir (III) Complexes with Substituted 1,10-Phenanthrolines: A New Class of Efficient Cationic Organometallic Second-Order NLO Chromophores. Chemistry. 2010 Mar 18.


Substitution of cyclometalated 2-phenylpyridine by the more pi delocalized 2-phenylquinoline (pq) or benzo [h] quinoline (bzq) or by the sulfur-containing 4,5-diphenyl-2-methyl-thiazole (dpmf) does not significantly affect the mubeta absolute value, which instead is affected by the nature of the R substituents on the phenanthroline, the higher value being associated with the electron-withdrawing NO (2) group.
0(0,0,0,0) Details
20355944 Kar S, Biswas S: Rapid Synthesis of Core/Shell ZnS:Mn/Si Nanotetrapods by a Catalyst-Free Thermal Evaporation Route. ACS Appl Mater Interfaces. 2009 Jul 29;1(7):1420-6.


At elevated temperature, chloride salt reacted with the sulfur vapor to produce S (2) Cl (2) gas that etched the Si wafers, generating Si vapor.
1(0,0,0,1) Details