Protein Information

Name complex is
Synonyms 39kD; CI 39kD; Complex I; Complex I 39kD; NADH dehydrogenase (ubiquinone) Fe S protein 2 like; NADH ubiquinone oxidoreductase 39 kDa subunit mitochondrial; NADH ubiquinone oxidoreductase 39 kDa subunit; NDUFA 9…

Compound Information

Name azobenzene
CAS diphenyldiazene

Reference List

PubMed Abstract RScore(About this table)
12240429 Kume S, Kurihara M, Nishihara H: Reversible trans-cis photoisomerization of azobenzene-attached bipyridine ligands coordinated to cobalt using a single UV light source and the Co (III)/Co (II) redox change. Chem Commun. 2001 Sep 7;(17):1656-7.

The trans/cis ratio of the azobenzene-attached bipyridine ligands in a cobalt complex is reversibly altered by a combination of photoirradiation with a single UV light source and the reversible redox change between Co (II) and Co (III).
81(1,1,1,1) Details
16716068 Fujita D, Murai M, Nishioka T, Miyoshi H: Light control of mitochondrial complex I activity by a photoresponsive inhibitor. Biochemistry. 2006 May 30;45(21):6581-6.

We speculated that if the shape of the side chains can be changed by the trans-cisphotoisomerization of the azobenzene unit that is introduced into the chain moiety, the inhibitory effect could be switched on and off in a reversible manner.
6(0,0,0,6) Details
667100 Birdi KS, Steinhardt J: The effects of diverse proteins on the solubilization of various hydrophobic probes by protein.detergent complexes. Biochim Biophys Acta. 1978 Jun 21;534(2):219-27.

The solubilization energy exhibited by each protein.detergent complex is largely determined by the individual protein, and by the charge on the detergent.
Sudan II, naphthalene, anthracene and azobenzene) in various protein.sodium dodecyl sulfate complexes, in order to enlarge the scope of our understanding of these phenomena, which undoubtedly play a part in the transport of different water-insoluble organic substances in the living organisms.
1(0,0,0,1) Details
14677959 Smith JM, Lachicotte RJ, Holland PL: N=N bond cleavage by a low-coordinate ironII hydride complex. . J Am Chem Soc. 2003 Dec 24;125(51):15752-3.

The complex is a dimer in the solid state, but spectroscopy and kinetics suggest that an orange three-coordinate monomer is in equilibrium with the dimer in solution.
The double bond of azobenzene is completely cleaved by heating with the hydride complex, and a hydrazido intermediate can be isolated.
1(0,0,0,1) Details
15651859 Komuro T, Matsuo T, Kawaguchi H, Tatsumi K: Synthesis of a vanadium (III) tris (arylthiolato) complex and its reactions with azide and azo compounds: formation of a sulfenamide complex via cleavage of an azo N=N bond. Inorg Chem. 2005 Jan 24;44(2):175-7.

This complex is found to undergo CH activation across a V-S bond in the presence of TMEDA to give a cyclometalated species along with free arylthiol.
Treatment of 1 with azobenzene produces an imide-sulfenamide compound, in which an azo N=N bond cleavage takes place concomitant with formation of a V=N and an S-N bond.
1(0,0,0,1) Details
17500707 Zakrevskyy Y, Stumpe J, Smarsly B, Faul CF: Photoinduction of optical anisotropy in an azobenzene-containing ionic self-assembly liquid-crystalline material. Phys Rev E Stat Nonlin Soft Matter Phys. 2007 Mar;75(3 Pt 1):031703. Epub 2007 Mar 7.

On the basis of all experimental results a model of the photoinduced alignment of the photochromic complex is proposed in which photoalignment of the material is connected to the reorientation of domains.
1(0,0,0,1) Details
12590551 Cacciapaglia R, Di Stefano S, Mandolini L: The bis-barium complex of a butterfly crown ether as a phototunable supramolecular catalyst. J Am Chem Soc. 2003 Feb 26;125(8):2224-7.

Reversible phototuning of the catalytic efficiency of the bis-barium complex of azobis (benzo-18-crown-6) in the basic ethanolysis of anilide derivatives has been achieved by light-induced cis right arrow over left arrow trans interconversion of the azobenzene spacer unit of the catalyst.
The geometry of the productive catalyst-substrate complex is more favorable when the concave cis form of the catalyst is involved.
1(0,0,0,1) Details
8521752 Zbaida S: The mechanism of microsomal azoreduction: predictions based on electronic aspects of structure-activity relationships. Drug Metab Rev. 1995;27(3):497-516.

Anaerobic cyclic voltammograms of azobenzene derivatives verify the following points: A nonsubstrate azo dye will not exhibit a positive potential. (Several nonsubstrate hydrazobenzenes exhibited positive potentials, but in a low range 0.41-0.48 V.
Estabrook et al. [111] suggested that carbon monoxide insensitivity can occur when the formation of ferrous cytochrome P450 substrate complex is rate limiting for the overall reaction.
1(0,0,0,1) Details
18965532 Danet AF, David V: Complexation, extraction and determination of the H (3) CHg (+) ion with cadion [1-(p-nitrophenyl)-3-(p'-azobenzene)-triazene]. Talanta. 1992 Oct;39(10):1299-306.

The complex is stable up to 180 degrees , and the reagent up to 140 degrees .
1(0,0,0,1) Details
14530092 Arakawa R, Yamaguchi T, Takahashi A, Fujimoto T, Kaneda T: Identification of face-to-face inclusion complex formation of cyclodextrin bearing an azobenzene group by electrospray ionization mass spectrometry. J Am Soc Mass Spectrom. 2003 Oct;14(10):1116-22.

The mass spectrometric study further demonstrated that the inclusion complex is formed through the interaction between the host CD cavity and the guest-substituent and that a contact complex is formed by hydrogen-bonding of the hydroxyl functions at the rims of the CD molecule.
1(0,0,0,1) Details
14562310 Turcitu D, Nief F, Ricard L: Structure and reactivity of homoleptic samarium (II) and thulium (II) phospholyl complexes. Chemistry. 2003 Oct 17;9(20):4916-23.


As expected, 5, 6 and 7 all reacted with azobenzene to give the trivalent complexes [Tm (dtp)(2)(N (2) Ph (2))] (13), [Sm (dsp)(2)(N (2) Ph (2))], (14) and [Sm (dtp)(2)(N (2) Ph (2))] (15), respectively; 13 and 14 were characterised by X-ray crystallography.
0(0,0,0,0) Details