| 19444858 |
Chandrashekhar N, Gayathri V, Nanje Gowda NM: Synthesis of rhodium (III) complexes with tris/tetrakis-benzimidazoles and benzothiazoles--quick identification of cyclometallation by nuclear magnetic resonance spectroscopy. Magn Reson Chem. 2009 Aug;47(8):666-73.
Reactions of rhodium (III) halides with multidentate N,S-heterocycles, (LH3) 1,3,5-tris (benzimidazolyl) benzene (L1H3; 1), 1,3,5-tris (N-methylbenzimidazolyl) benzene (L2H3; 2) and 1,3,5-tris (benzothiazolyl) benzene (L3H3; 3), in the molar ratio 1:1 in methanol-chloroform produced mononuclear cyclometallated products of the composition [RhX2 (LH2)(H2O)] (X = Cl, Br, I; LH2 = L1H2, L2H2, L3H2). |
82(1,1,1,2) |
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