Protein Information

Name CCl 3
Synonyms CCL 3; CCL3; G0/G1 switch regulatory protein 19 1; G0S19 1; G0S19 1 protein; LD78 alpha; LD78ALPHA; MIP 1 alpha Tonsillar lymphocyte LD78 alpha protein…

Compound Information

Name chloroform
CAS trichloromethane

Reference List

PubMed Abstract RScore(About this table)
19199302 Wu CY, Chou HH, Lin YC, Wang Y, Liu YH: Reactions of ruthenium vinylidene and acetylide complexes containing trichloromethyl groups: preparation of a cyclobutenonyl complex by solid-state photolysis. Chemistry. 2009;15(13):3221-9.

A rare chloroform elimination was observed when 2 was treated with nBu (4) NOH to give neutral acetylide complex [Ru (2)]--C [triple chemical bond] CC (==O) CCl (3) (3).
81(1,1,1,1) Details
20059084 Mehlenbacher RD, Lyons B, Wilson KC, Du Y, McCamant DW: Theoretical analysis of anharmonic coupling and cascading Raman signals observed with femtosecond stimulated Raman spectroscopy. J Chem Phys. 2009 Dec 28;131(24):244512.

Experiments probing deuterochloroform find significant sidebands of the CCl (3) bend, which has an E type symmetry, shifted from the A (1) type C-D and C-Cl stretching modes, despite the fact that third-order anharmonic coupling between these modes is forbidden by symmetry.
Experiments probing a 50:50 mixture of chloroform and d-chloroform find equivalent intensity signals of low-frequency CDCl (3) modes as sidebands shifted from both the C-D stretch of CDCl (3) and the C-H stretch of CHCl (3).
1(0,0,0,1) Details
18958324 Seidl AJ, Cohen LR, Pena LA, Hoggard PE: Chlorochromate ion as a catalyst for the photodegradation of chloroform by visible light. Photochem Photobiol Sci. 2008 Nov;7(11):1373-7. Epub 2008 Sep 19.

It is proposed that, at least initially, a cycle involving photoreduction of a Cr (vi) species and thermal reoxidation of Cr (v) by CCl (3) OOH produces radicals that initiate further decomposition.
1(0,0,0,1) Details