| 18060125 |
Boomishankar R, Ledger J, Guilbaud JB, Campbell NL, Bacsa J, Bonar-Law R, Khimyak YZ, Steiner A: The N-donor stabilised cyclotriphosphazene hexacation [P3N3 (DMAP) 6] 6+. Chem Commun. 2007 Dec 28;(48):5152-4. Epub 2007 Oct 10.
The cyclotriphosphazene P (3) N (3) Cl (6) reacts with six equivalents of DMAP (4-(dimethylamino) pyridine) in superheated chloroform to form crystals of composition [P (3) N (3)(DMAP)(6)] Cl (6).19CHCl (3) comprising [P (3) N (3)(DMAP)(6)](6+) ions, which host five chloride ions in basket-type cavities on either side of the ring and at equatorial positions via tetradentate ortho-H-donor arrangements. |
81(1,1,1,1) |
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