| Name | Cl 2 |
|---|---|
| Synonyms | AMB11; MHC class I NK cell receptor; CD158E1; CD158E1/2; CD158E2; CL 11; CL 2; HLA BW4 specific inhibitory NK cell receptor… |
| Name | sulfoxide |
|---|---|
| CAS | 5-[2-(octylsulfinyl)propyl]-1,3-benzodioxole |
| PubMed | Abstract | RScore(About this table) | |
|---|---|---|---|
| 19921058 | Takemura Y, Nakajima T, Tanase T: Interconversion between ladder-type octanuclear and linear tetranuclear (I) complexes supported by tetraphosphine ligands. Dalton Trans. 2009 Dec 14;(46):10231-43. Epub 2009 Oct 16. When complex 8c was treated with AgPF (6) in a CH (3) CN-CH (2) Cl (2) mixed solvent, the soft Lewis acidic Ag (I) ions took the (I)-binding dpmppm off and the resultant two {Cu (4)(mu-I)(3)(mu-dpmppm)((t) BuNC)(2)}(+) fragments were zipped up to form the ladder-type octacopper (I) complex, [Cu (8)(mu-I)(6)(mu-dpmppm)(2)((t) BuNC)(2)](PF (6))(2) (9). |
1(0,0,0,1) | Details |
| 19789766 | Jose Calhorda M, Jorge Costa P: Expanding the role of oxo- (VI) catalysts: a DFT interpretation of X-H activation leading to reduction or oxidation. Dalton Trans. 2009 Oct 21;(39):8155-61. Epub 2009 Aug 5. Organometallic complexes of transition metals in high oxidation states, namely Re (v) and Mo (vi), have been shown experimentally to catalyze a variety of reduction reactions, such as hydrosilylation of ketones, alkyne hydrogenation, sulfoxide reduction (deoxygenation), etc, often under mild conditions and with high yields and selectivity. We describe a series of DFT calculations, showing that most X-H bonds are activated by [MoO (2) Cl (2)], forming a hydride complex, which is the catalytic active species in catalysis. |
1(0,0,0,1) | Details |
| 19882593 | Kobetic R, Gembarovski D, Visnjevac A, Zinic B, Gabelica-Markovic V: ESI-MS studies of palladium (II) complexes with 1-(p-toluenesulfonyl) /cytosinato ligands. J Mass Spectrom. 2010 Jan;45(1):51-64. The mononuclear complex Pd (1-TosC-N3)(2) Cl (2) (2) containing 1-(p-toluenesulfonyl) (1) as a ligand, as well as dinuclear complexes Pd (2)(1-TosC (-)-N3,N4)(4) (3) and Pd (2)(1-TosC (-)-N3,N4)(2) DMSO (2) Cl (2) (4) containing the ligand anion (1-TosC (-)), was mass analyzed by electrospray ionization ion trap MS/MS and high resolution MS. |
1(0,0,0,1) | Details |
| 18264576 | Hanson P, Hendrickx RA, Smith JR: An investigation by means of correlation analysis into the mechanisms of oxidation of aryl methyl sulfides and sulfoxides by dimethyldioxirane in various solvents. Org Biomol Chem. 2008 Feb 21;6(4):745-61. Epub 2008 Jan 11. Here, the behaviour of the reaction is consistent with a two-step mechanism in which the oxidant reversibly attacks the sulfide to form an open-chain sulfonium that subsequently fragments to sulfoxide and |
0(0,0,0,0) | Details |
| 17580938 | Lee DH, Hatcher LQ, Vance MA, Sarangi R, Milligan AE, Sarjeant AA, Incarvito CD, Rheingold AL, Hodgson KO, Hedman B, Solomon EI, Karlin KD: (I) complex O (2)-reactivity with a N (3) S thioether ligand: a -dioxygen adduct including ligation, ligand oxygenation, and comparisons with all ligand analogues. Inorg Chem. 2007 Jul 23;46(15):6056-68. Epub 2007 Jun 20. At low temperature in CH (2) Cl (2), or 2-methyltetrahydrofuran (MeTHF), 1 reacts with O (2) and generates an adduct formulated as an end-on peroxodicopper (II) complex [{Cu (II)(L (N3S))}(2)(mu-1,2-O (2)(2-))](2+) (4)){lambda (max) = 530 (epsilon approximately 9200 M (-1) cm (-1)) and 605 nm (epsilon approximately 11,800 M (-1) cm (-1))}; the number and relative intensity of LMCT UV-vis bands vary from those for [{Cu (II)(TMPA)}(2)(O (2)(2-))](2+) {lambda (max) = 524 nm (epsilon = 11,300 M (-1) cm (-1)) and 615 nm (epsilon = 5800 M (-1) cm (-1))} and are ascribed to electronic structure variation due to coordination geometry changes with the L (N3S) ligand. Following a [Cu (I)(L (N3S))](+)/O (2) reaction and warming, the L (N3S) thioether ligand is oxidized to the sulfoxide in a reaction modeling monooxygenase activity. |
1(0,0,0,1) | Details |
| 18688431 | Bednarek E, Sitkowski J, Kawecki R, Kozerski L, Bocian W, Pazderski L, Priebe W: Structure and dynamics of methyl cis-3,4-diamino-2,3,4,6-tetradeoxy-alpha-L-lyxo-hexopyranoside complexes with PtCl (2) and PdCl (2), by (1) H, (2) H, (13) C, (15) N and (195) Pt NMR spectroscopy in DMSO, CD (3) CN and H (2) O. Dalton Trans. 2008 Aug 21;(31):4129-37. Epub 2008 Jul 8. Pd (II) and Pt (II) complexes with LL = methyl cis-3,4-diamino-2,3,4,6-tetradeoxy-alpha-l-lyxo-hexopyranoside of the formulae [Pd (LL) Cl (2)] and [Pt (LL) Cl (2)], 1, were studied by (1) H, (2) H, (13) C, (15) N and (195) Pt NMR spectroscopy. |
2(0,0,0,2) | Details |