| 19166363 |
Lampropoulos C, Abboud KA, Stamatatos TC, Christou G: A nontwisted, ferromagnetically coupled Mn (III) 3O triangular complex from the use of 2,6-bis (hydroxymethyl)-p-cresol. Inorg Chem. 2009 Feb 2;48(3):813-5.
The reaction between Mn (O (2) CMe)(2) x 4 H (2) O and hmcH (3) [hmcH (3) = 2,6-bis (hydroxymethyl)-p-cresol] in CH (2) Cl (2) in the presence of NEt (3) affords the Mn (III)(3) complex [NEt (3)(CH (2) Cl)](2)[Mn (3) O (hmcH)(3)(hmcH (2))(3)] (1). The anion of 1 contains a [Mn (III)(3)(mu (3)-O)](7+) triangular core, with the central O (2-) ion lying above the Mn (3) plane. The complex is ferromagnetically coupled with a resulting S = 6 ground state. |
1(0,0,0,1) |