| 19759931 |
Jura M, Levason W, Reid G, Webster M: Isolation and structures of sulfonium salts derived from thioethers: [{o-C (6) H (4)(CH (2) SMe)(2)}H][NbF (6)] and [{[9] aneS (3)}H][NbF (6)]. Dalton Trans. 2009 Oct 7;(37):7610-2. Epub 2009 Jul 29.
Two very unusual sulfonium salts, [{o-C (6) H (4)(CH (2) SMe)(2)}H][NbF (6)] and [{[9] aneS (3)}H][NbF (6)], obtained from reaction of the thioethers with NbF (5) in CH (2) Cl (2) solution, are reported and their structures described; the eight-coordinate tetrafluoro Nb (v) cation of the dithioether is obtained from the same reaction. |
6(0,0,1,1) |