| 14532651 |
Wang Y, Li YZ, Jin QH, Zheng HG, Hu Z, Xin XQ: Tris [diphenyl (2-pyridyl) phosphine]-micro (3)-iodo-tri-micro (3)-sulfido-sulf idotrisilvertungsten dichloromethane hemisolvate. Acta Crystallogr C. 2003 Oct;59(Pt 10):M390-1. Epub 2003 Sep 16.
The title compound, [Ag (3) WIS (4)(C (17) H (14) NP)(3)].0.5CH (2) Cl (2), is a cubane-type heterometallic cluster containing diphenyl (2-pyridyl) phosphine (Ph (2) PPy). The pyridyl group of Ph (2) PPy remains uncoordinated, so the Ph (2) PPy ligand is monodentate and coordinates to one Ag atom. The W atom and three Ag atoms form a distorted tetrahedral geometry, capped by one I atom and three S atoms. |
6(0,0,1,1) |