Name | Cl 2 |
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Synonyms | AMB11; MHC class I NK cell receptor; CD158E1; CD158E1/2; CD158E2; CL 11; CL 2; HLA BW4 specific inhibitory NK cell receptor… |
Name | sulfur |
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CAS | sulfur |
PubMed | Abstract | RScore(About this table) | |
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19746999 | Han YG, Xu C, Duan T, Wu FH, Zhang QF, Leung WH: Heterometallic aggregates of ethane-1,2-dithiolate): syntheses and structures of [Sn (edt) 2Cl (mu-I)(mu3-I)(CuPPh3) 3], [Sn (edt) 2 (mu-Br) 2 (mu3-Br) 2 (CuPPh3) 4], and [{Sn (edt) 2}3 (mu-OH) 3Cu5 (PPh3) 8][PF6] 2. Inorg Chem. 2009 Sep 21;48(18):8796-802. The treatment of a slurry of an equimolar mixture of [Sn (edt)(2)] (edt = ethane-1,2- dithiolate) and [Et (4) N] Cl.xH (2) O with CuI in the presence of PPh (3) gave a tetranuclear compound, [Sn (edt)(2) Cl (mu-I)(mu (3)-I)(CuPPh (3))(3)] (1), which consists of a rectangular-pyramidal [Sn (edt)(2) Cl](-) moiety ligated by three [Cu (PPh (3))](+) fragments via the sulfur atoms of the edt (2-) ligands. Reaction of [Sn (edt)(2)] with [Cu (MeCN)(4)][PF (6)] and PPh (3) in a mixed MeCN/CH (2) Cl (2) solution yielded a novel octanuclear compound, [{Sn (edt)(2)}(3)(mu-OH)(3) Cu (5)(PPh (3))(8)][PF (6)](2) (3), which may be described as a triangular [{Sn (edt)(2)}(3)(mu-OH)(3)](3-) core chelated by three [Cu (PPh (3))(2)](+) species and capped by two [Cu (PPh (3))](+) species. |
(I) with metalloligand Sn (edt) 2 (edt = 3(0,0,0,3) | Details |
19432428 | Milsmann C, Bothe E, Bill E, Weyhermuller T, Wieghardt K: Octahedral Monodithiolene Complexes of Cobalt (III) and Chromium (III). Inorg Chem. 2009 May 11. Comparison with the corresponding o-benzosemiquinonate (1-) complexes shows that the S,S'-coordinated -1,2-dithiolate (1-) radical is a sulfur centered radical whereas its containing analogue carries approximately 65% of the spin density on the six-membered ring. The reaction of [M (tren) Cl (2)] Cl (M = Co (III), Cr (III)) with -1,2-dithiol, H (2)(bdt), and 3,6-bis (trimethylsilyl) -1,2-dithiol, H (2)(tmsdt), in a water/ mixture in the presence of tert-butoxide produced green crystals of [M (tren)(bdt)](PF (6))(1/2)(Cl)(1/2).H (2) O (1 (PF (6))(1/2)(Cl)(1/2).H (2) O, M = Co; 2 (PF (6))(1/2)(Cl)(1/2).H (2) O, M = Cr) and [M (tren)(tmsdt)](PF (6))(1/2)(Cl)(1/2).H (2) O (1a (PF (6))(1/2)(Cl)(1/2).H (2) O, M = Co; 2a (PF (6))(1/2)(Cl)(1/2).H (2) O, M = Cr), respectively, upon addition of KPF (6). |
2(0,0,0,2) | Details |
20104915 | Tuncaboylu DC, Okay O: Hierarchically Macroporous Cryogels of Polyisobutylene and The gels were prepared by cross-linking of butyl rubber in cyclohexane containing nanoparticles using sulfur monochloride (S (2) Cl (2)) as a cross-linking agent. |
Nanoparticles. Langmuir. 2010 Jan 28.6(0,0,1,1) | Details |
19449357 | Decken A, Knapp C, Nikiforov GB, Passmore J, Rautiainen JM, Wang X, Zeng X: Silver (I) complexes of the weakly coordinating solvents SO (2) and CH (2) Cl (2): crystal structures, bonding, and energetics of [Ag (OSO)][Al{OC (CF (3))(3)}(4)], [Ag (OSO)(2/2)][SbF (6)], and [Ag (CH (2) Cl (2))(2)][SbF (6)]. Chemistry. 2009 Jun 22;15(26):6504-17. Pushing the limits of coordination chemistry: The most weakly coordinated silver complexes of the very weakly coordinating solvents dichloromethane and liquid sulfur dioxide were prepared. |
5(0,0,0,5) | Details |
20043673 | Ohmae T, Nishinaga T, Wu M, Iyoda M: Cyclic tetrathiophenes planarized by sulfur bridges bearing antiaromatic cyclooctatetraene core: syntheses, structures, and properties. J Am Chem Soc. 2010 Jan 27;132(3):1066-74. Furthermore the colors of the solutions of 1 (lambda (max) = 483 nm), 2b (lambda (max) = 618 nm), and 3b (lambda (max) = 575 nm) were orange, purple, and red in CH (2) Cl (2), respectively, indicating that the HOMO-LUMO gaps of 1-3 become increasingly narrow with increasing planarity of the COT ring. |
and 1(0,0,0,1) | Details |
19789783 | Bowmaker GA, Chaichit N, Hanna JV, Pakawatchai C, Skelton BW, White AH: Spectroscopy and structures of two complete families, one mononuclear, the other binuclear, of 1 : 2 CuX : dptu stoichiometry (X = Cl, Br, I; 'dptu' = N,N'-diphenylthiourea). Dalton Trans. 2009 Oct 21;(39):8308-16. Epub 2009 Aug 13. A (solvated) salt is found to be of the form [Cu (dptu)(2)](2)(SO (4)), providing a novel example of a (i) atom being (quasi-) linearly coordinated by the pair of unidentate (dptu) sulfur ligands, Cu-S 2.1770 (5), 2.1811 (5) A, S-Cu-S 162.18 (2) degrees . The broadline static (65) Cu NMR spectra of [Cl (2) Cu (2)(dptu)(4)].2CH (3) CN and [X (2) Cu (2)(dptu)(4)] (X = Br, I) have been recorded at 9.4 and 7.05 T, and the spectra have been analysed to yield the (65) Cu nuclear quadrupole coupling and chemical shift parameters. |
1(0,0,0,1) | Details |
19575350 | Wright RJ, Lim C, Tilley TD: Diiron reduction catalysts possessing electron-rich and electron-poor naphthalene-1,8-dithiolate ligands. Chemistry. 2009 Aug 24;15(34):8518-25. Cyclic voltammetry (CH (2) Cl (2)/nBu (4) PF (6)) revealed two one-electron reductions, at potentials more positive than those for the related [Fe (2)(CO)(6)(S (CH (2))(3) S)] (1), and one one-electron oxidation. |
1(0,0,0,1) | Details |
19924962 | Gendel Y, Levi N, Lahav O: H2S (g) removal using a modified, low-ph liquid redox sulfur recovery (LRSR) process with electrochemical regeneration of the Fe catalyst couple. Environ Sci Technol. 2009 Nov 1;43(21):8315-9. Fe (II) was oxidized in a flow-through electrolytic cell by Cl (2 (aq)) formed on a Ti/RuO (2) anode. pH 1.0 was applied to retard the potential precipitation of predominantly jarosite group Fe (III) species. |
1(0,0,0,1) | Details |
20018556 | Krishnan S, Laly K, Prathapachandra Kurup MR: Synthesis and spectral investigations of Mn (II) complexes of pentadentate bis (thiosemicarbazones). Spectrochim Acta A Mol Biomol Spectrosc. 2010 Feb;75(2):585-8. Epub 2009 Nov 18. Five Mn (II) complexes of bis (thiosemicarbazones) which are represented as [Mn (H (2) Ac4Ph) Cl (2)] (1), [Mn (Ac4Ph) H (2) O] (2), [Mn (H (2) Ac4Cy) Cl (2)].H (2) O (3), [Mn (H (2) Ac4Et) Cl (2)].3H (2) O (4) and [Mn (H (2) Ac4Et)(OAc)(2)].3H (2) O (5) have been synthesized and characterized by elemental analyses, electronic, infrared and EPR spectral techniques. In all the complexes except [Mn (Ac4Ph) H (2) O], the ligands act as pentadentate neutral molecules and coordinate to Mn (II) ion through two thione sulfur atoms, two azomethine nitrogens and the suggesting a heptacoordination. |
1(0,0,0,1) | Details |
19572498 | Milsmann C, Patra GK, Bill E, Weyhermuller T, DeBeer George S, Wieghardt K: Octahedral monodithiolene complexes of iron: characterization of S,S'-coordinated dithiolate (1-) pi radical monoanions: a spectroscopic and density functional theoretical investigation. Inorg Chem. 2009 Aug 3;48(15):7430-45. The reaction of cis-[Fe (III)(cyclam) Cl (2)] Cl with 1 equiv of N-diethyldithiocarbamate, toluene-3,4-dithiolate, and maleonitriledithiolate in in the presence of triethylamine afforded the cations [Fe (III)(cyclam)(Et (2) dtc)](2+) (1), [Fe (III)(cyclam)(tdt)](+) (2), and [Fe (III)(cyclam)(mnt)](+) (3), which were isolated as triflate, hexafluorophosphate, and tetrafluoroborate salt, respectively, using triflate, hexafluorophosphate, or tetrafluoroborate as the source for the counteranion. The analysis of the sulfur K pre-edge transitions reveals significant multiplet effects in the spectra of 2 and 2 (ox), which provide rare experimental evidence for a singlet diradical description for 2 (ox). |
1(0,0,0,1) | Details |
19893229 | Dols TS, Spaniol TP, Okuda J: Titanium complexes with sulfur-linked bis (phenolate) ligands. . Acta Crystallogr C. 2009 Nov;65(Pt 11):m443-6. Epub 2009 Oct 24. High-quality crystals of two bis (phenolate) titanium complexes, namely dichlorido{4,4'-dimethyl-2,2'-[cyclohexane-1,2-diylbis (sulfanediyl)] diphen olato}titanium (IV), [Ti (C (20) H (22) O (2) S (2)) Cl (2)], (I), and dichlorido{2,2'-[cyclohexane-1,2-diylbis (sulfanediyl)] diphenolato}titanium (IV), [Ti (C (18) H (18) O (2) S (2)) Cl (2)], (II), were obtained by reactive crystallization. |
1(0,0,0,1) | Details |
20301142 | Valore A, Cariati E, Dragonetti C, Righetto S, Roberto D, Ugo R, De Angelis F, Fantacci S, Sgamellotti A, Macchioni A, Zuccaccia D: Cyclometalated Ir (III) Complexes with Substituted 1,10-Phenanthrolines: A New Class of Efficient Cationic Organometallic Second-Order NLO Chromophores. Chemistry. 2010 Mar 18. Substitution of cyclometalated 2-phenylpyridine by the more pi delocalized 2-phenylquinoline (pq) or benzo [h] quinoline (bzq) or by the sulfur-containing 4,5-diphenyl-2-methyl-thiazole (dpmf) does not significantly affect the mubeta absolute value, which instead is affected by the nature of the R substituents on the phenanthroline, the higher value being associated with the electron-withdrawing NO (2) group. |
0(0,0,0,0) | Details |
20355944 | Kar S, Biswas S: Rapid Synthesis of Core/Shell ZnS:Mn/Si Nanotetrapods by a Catalyst-Free Thermal Evaporation Route. ACS Appl Mater Interfaces. 2009 Jul 29;1(7):1420-6. At elevated temperature, salt reacted with the to produce S (2) Cl (2) gas that etched the Si wafers, generating Si vapor. |
1(0,0,0,1) | Details |