| 19030628 |
Beheshti A, Clegg W, Nobakht V, Panahi Mehr M, Russo L: Complexes of copper (I) and silver (I) with bis (methimazolyl) borate and dihydrobis (2-mercaptothiazolyl) borate ligands. Dalton Trans. 2008 Dec 14;(46):6641-6. Epub 2008 Oct 16.
In complexes 2-4, the metal atom is found in a distorted trigonal-planar geometry, bound by a terminal phosphine ligand and two sulfur atoms of a chelating ligand, supplemented by an MH-B interaction, which appears to be a common feature in the coordination chemistry of the (BmMe)- and [H2B (tiaz) 2]- ligands; compounds 1-4 are the first reported complexes of copper (I) and silver (I) with any bis (2-mercaptoimidazolyl) borate ligand or with H2B (tiaz) 2. |
82(1,1,1,2) |
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