Protein Information

Name HL 2
Synonyms DNAH 6; HL2; Dynein heavy chain; DNAH6; Dnahc6; HL 2; Dnahc6s

Compound Information

Name phosphine
CAS phosphine

Reference List

PubMed Abstract RScore(About this table)
17048289 Liu B, Cui D, Ma J, Chen X, Jing X: Synthesis and reactivity of rare earth metal alkyl complexes stabilized by anilido phosphinimine and amino phosphine ligands. Chemistry. 2007;13(3):834-45.

Treatment of [Ln{CH (2) Si (CH (3))(3)}(3)(thf)(2)] with amino phosphine ligands HL (2-R) gave stable rare earth metal bis-alkyl complexes [(L (2-R)) Ln{CH (2) Si (CH (3))(3)}(2)(thf)] (4 a: Ln=Y, R=Me; 4 b: Ln=Lu, R=Me; 4 c: Ln=Y, R=iPr; 4 d: Ln=Y, R=iPr) in high yields.
81(1,1,1,1) Details
19507885 Marchetti F, Pettinari C, Cerquetella A, Cingolani A, Pettinari R, Monari M, Wanke R, Kuznetsov ML, Pombeiro AJ: Switching between kappa (2) and kappa (3) Bis (pyrazol-1-yl) acetate Ligands by Tuning Reaction Conditions: Synthesis, Spectral, Electrochemical, Structural, and Theoretical Studies on Arene-Ru (II) Derivatives of Bis (azol-1-yl) acetate Ligands. Inorg Chem. 2009 Jun 9.

New (arene) ruthenium (II) derivatives containing neutral HL or anionic L (-) ligands (arene = p-cymene or benzene, HL in general, in particular HL (1) = bis (pyrazol-1-yl) acetic acid and HL (2) = bis (3,5-dimethylpyrazol-1-yl) acetic acid) have been synthesized and analytically and spectrally characterized.
The ligands in neutral form coordinate ruthenium in a chelating kappa (2)-N,N'-bidentate fashion affording 1:1 derivatives of formula [Ru (arene)(HL) Cl] Cl, where the inner Cl can be replaced by a phosphine.
1(0,0,0,1) Details
12763666 Nomiya K, Yamamoto S, Noguchi R, Yokoyama H, Kasuga NC, Ohyama K, Kato C: Ligand-exchangeability of 2-coordinate phosphinegold (I) complexes with AuSP and AuNP cores showing selective antimicrobial activities against Gram-positive bacteria. J Inorg Biochem. 2003 Jun 1;95(2-3):208-20.


As a model reaction of phosphinegold (I) complexes with the cysteine residue in the biological ligands, we examined if the ligand exchange reactions of the aromatic anions L (1)(-) in [Au (L (1))(PPh (3))] (HL (1)=6-H (2) mna 2, 2-H (2) mna 3, 2-H (2) mba 6, Hpz 9, Him 10, 1,2,3-Htriz 11, 1,2,4-Htriz 12) with aliphatic thiols HL (2) (HL (2)=2-H (2) mpa, D-H (2) pen) occurred under the mild conditions and, also, if the 'reverse' reactions, namely, the ligand exchange reactions of the thiolate anions in [Au (2-Hmpa)(PPh (3))] 1, [Au (D-Hpen)(PPh (3))] 4 and [Au (2-Hmba)(PPh (3))] 6 with the free ligands HL (1) took place under similar conditions.
1(0,0,0,1) Details