| Name | prop 1 |
|---|---|
| Synonyms | Homeobox protein prophet of PIT 1; PROP 1; PROP1; Pituitary specific homeodomain factor; Pituitary specific homeodomain factors |
| Name | phosphine |
|---|---|
| CAS | phosphine |
| PubMed | Abstract | RScore(About this table) | |
|---|---|---|---|
| 19445512 | Zhang Y, Pullarkat SA, Li Y, Leung PH: Asymmetric synthesis of diphosphine ligands containing and carbon stereogenic centers by means of a chiral palladium complex promoted hydrophosphination reaction. Inorg Chem. 2009 Jun 15;48(12):5535-9. An organopalladium complex containing ortho-metalated (R)-(1-(dimethylamino) ethyl) naphthalene as the chiral auxiliary has been used to promote the asymmetric hydrophosphination reaction between diphenylphosphine and phenyldi [(Z)-prop-1-enyl] phosphine in high regio- and stereoselectivity under mild conditions. |
31(0,1,1,1) | Details |
| 14659671 | Horne G, Mills SJ, Potter BV: First derivatives of 1,4,6-trisphosphate modified at positions 2 and 3: structural analogues of Carbohydr Res. 2004 Jan 2;339(1):51-65. Deblocking of p-methoxybenzyl groups was accomplished with TFA in dichloromethane and the allyl groups were removed by isomerisation to the cis-prop-1-enyl derivative, which was hydrolysed under acidic conditions to give the corresponding 1,4,6-triol. The 1,4,6-triols were phosphitylated with the P (III) reagent bis (benzyloxy)(diisopropylamino) phosphine in the presence of 1H-tetrazole then oxidised with 3-chloroperoxybenzoic acid followed by deblocking by hydrogenolysis to give DL-2-O-methyl-, DL-3-O-deoxy-, DL-3-O-deoxy-2-O-methyl-, DL-3-O-(2-hydroxyethyl)-, DL-3-O-(3-hydroxypropyl)- and DL-3-O-(4-hydroxybutyl)- 1,4,6-trisphosphate, respectively. |
1(0,0,0,1) | Details |