Protein Information

Name AgX
Synonyms AGX; AGX 1; AGX1; AgX; Antigen X; SPAG 2; SPAG2; Sperm associated antigen 2…

Compound Information

Name phosphine
CAS phosphine

Reference List

PubMed Abstract RScore(About this table)
18279959 Hadjikakou SK, Ozturk II, Xanthopoulou MN, Zachariadis PC, Zartilas S, Karkabounas S, Hadjiliadis N: Synthesis, structural characterization and biological study of new organotin (IV), silver (I) and antimony (III) complexes with thioamides. J Inorg Biochem. 2008 May-Jun;102(5-6):1007-15. Epub 2008 Jan 8.

The results are compared with the corresponding ones found for the silver (I) complexes of formulae complexes {[Ag6 (mu3-HMNA) 4 (mu3-MNA) 2](2-).[(Et (3) NH)+] 2.(DMSO) 2.(H2O)} (13), {[Ag4Cl4 (mu3-STHPMH2) 4] n} (14), {[Ag6 (mu2-Br) 6 (mu2-STHPMH2) 4 (mu3-STHPMH2) 2] n} (15), {[Ag4 (mu2STHPMH2) 6](NO3) 4}(n) (16), {[AgCl (TPTP)] 4} (17), [AgX (TPTP) 3] with X=Cl (18), Br (19), I (20) (where STHPMH2=2-mercapto-3,4,5,6-tetrahydro-pyrimidine, TPTP=tri (p-toly) phosphine) and those of antimony (III) complexes {[SbCl2 (MBZIM) 4](+).Cl (-).2H2O.(CH3OH)} (21), {[SbCl2 (MBZIM) 4]+.Cl (-).3H2O.(CH3CN)} (22), [SbCl3 (MBZIM) 2] (23), [SbCl3 (EMBZIM) 2] (24), [SbCl3 (MTZD) 2] (25), {[SbCl3 (THPMT) 2]} (26) and {[Sb (PMT) 3].0.5 (CH3OH)} (27) (where MBZIM is 2-mercapto-benzimidazole, EMBZIM=5-ethoxy-2-mercapto-benzimidazole and MTZD is 2-mercapto-thiazolidine), which they have characterized with similar techniques as in case of organotin (IV) complexes.
31(0,1,1,1) Details
17083218 Kannan S, Moody MA, Barnes CL, Duval PB: Fluoride abstraction and reversible photochemical reduction of cationic uranyl (VI) phosphine oxide complexes. Inorg Chem. 2006 Nov 13;45(23):9206-12.

The syntheses, structural and spectroscopic characterization, fluoride abstraction reactions, and photochemical reactivity of cationic uranyl (VI) phosphine oxide complexes are described. [UO2 (OPPh3) 4][X] 2 (1a, X = OTf; 1b, X = BF4) and [UO2 (dppmo) 2 (OPPh3)][X] 2 (2a, X = OTf; 2b, X = BF (4)) are prepared from the corresponding uranyl (VI) chloride precursor and 2 equiv each of AgX and phosphine oxide.
31(0,1,1,1) Details
20063851 Bergbreiter DE, Yang YC: Variable-temperature NMR studies of soluble polymer-supported phosphine-silver complexes. J Org Chem. 2010 Feb 5;75(3):873-8.

The results show that the dynamic behavior of the PIB- and isobutyldiphenylphosphine-AgX complexes is nearly identical based on line-shape analysis of these (31) P NMR spectra as a function of temperature.
2(0,0,0,2) Details
14982415 Rivard E, Huynh K, Lough AJ, Manners I: Donor-stabilized cations and imine transfer from N-silylphosphoranimines. J Am Chem Soc. 2004 Mar 3;126(8):2286-7.

A series of donor-stabilized N-silylphosphoranimine salts [DMAP.PCl2=NSiMe3]+X- (DMAP = 4-(dimethylamino) pyridine) were prepared by the reaction of Cl3P=NSiMe3 with DMAP in the presence of silver salts AgX (X = OSO2CF3, BF4, and SbF6).
Attempts to stabilize a N-silylphosphoranimine cation with phosphine donors led to unexpected imine transfer chemistry.
2(0,0,0,2) Details
18507374 Fernandez-Anca D, Garcia-Seijo MI, Castineiras A, Garcia-Fernandez ME: Novel chelate ring-opening induced by silver (I) of five-coordinate palladium (II) and platinum (II) complexes containing tripodal polyphosphines. Inorg Chem. 2008 Jul 7;47(13):5685-95. Epub 2008 May 29.


The ionic complexes [Pd (NP 3) X] X [NP 3 = tris [2-(diphenylphosphino) ethyl] amine, X = Cl (1), Br (2)] and [M (PP 3) X] X [PP 3 = tris [2-(diphenylphosphino) ethyl] phosphine, M = Pd, X = Cl (3), Br (4); M = Pt, X = Cl (5), Br (6)] contain square pyramidal (1, 2) and trigonal bipyramidal (3- 6) cations with three fused chelate rings to M and one M-X bond.
0(0,0,0,0) Details