| Name | NEt 2 |
|---|---|
| Synonyms | NET 2; NET2; TM4SF12; TSPAN12; Tetraspan NET 2; Tetraspan NET2; Tetraspanin 12; Transmembrane 4 superfamily member 12… |
| Name | phosphine |
|---|---|
| CAS | phosphine |
| PubMed | Abstract | RScore(About this table) | |
|---|---|---|---|
| 19658426 | Maulana I, Lonnecke P, Hey-Hawkins E: Platinum (II) and palladium (II) complexes of chiral P-Cl functionalized bis-phosphino ortho-carbaboranes. Inorg Chem. 2009 Sep 7;48(17):8638-45. Platinum (II) and palladium (II) complexes of chiral P-Cl functionalized bis-phosphino ortho-carbaborane are readily obtained from reactions of chiral bidentate phosphino carbaborane ligands rac-1,2-(PRCl)(2)(C (2) B (10) H (10)) with [MCl (2)(COD)] (M = Pd, Pt; COD = 1,5-cyclooctadiene) to give cis-rac-[MCl (2){1,2-(PRCl)(2)(C (2) B (10) H (10))}] (M = Pt, Pd; R = (t) Bu, Ph, NEt (2), NPh (2)). cis-rac-[MCl (2){1,2-(P (t) BuCl)(2)(C (2) B (10) H (10))}] [M = Pt (1), Pd (6)] decompose in solution in toluene or dichloromethane at room temperature over several weeks with formation of the corresponding dinuclear platinum and palladium complex with two nido-carbaboranyl phosphine ligands, (R (P),R (P),S (P),S (P))-[{M (7,8-{P (t) BuCl}(2) C (2) B (9) H (10))(mu-Cl)}(2)] [M = Pt (2), Pd (7)], among other decomposition products. |
31(0,1,1,1) | Details |
| 19117419 | Azouri M, Andrieu J, Picquet M, Cattey H: Synthesis of new cationic donor-stabilized phosphenium adducts and their unexpected P-substituent exchange reactions. Inorg Chem. 2009 Feb 2;48(3):1236-42. The reaction between two 1,3-dialkylimidazolium-2-carboxylates 1a and 1b and two different dichlorophosphines (RPCl (2), with R = Ph and NEt (2)) led to new donor-stabilized phosphenium adducts. When the reaction was performed with the 1,3-dimethylimidazolium-2-carboxylate 1a and PhPCl (2) in a 2:1 ratio, the phosphine 4a, bearing two imidazolium moieties, was obtained and led to 5a, after an anion exchange reaction with KPF (6), the latter being fully characterized by an X-ray structure analysis. |
1(0,0,0,1) | Details |