| Name | PPh 2 |
|---|---|
| Synonyms | PPH 2; PPH2; primary pulmonary hypertension 2; primary pulmonary hypertension 2s |
| Name | phosphine |
|---|---|
| CAS | phosphine |
| PubMed | Abstract | RScore(About this table) | |
|---|---|---|---|
| 17117215 | Huang YL, Chang CP, Hong FE: insertion in a carbon- bond of the phenylethynyl-di-(tert-butyl)-phosphine bridged dicobalt complex: exploring the nature of migration using DFT. Dalton Trans. 2006 Dec 14;(46):5454-63. Epub 2006 Oct 18. In the process of isolation under aerobic conditions phenylethynyl-di-(tert-butyl)-phosphine bridged dicobalt complex [(micro-PPh (2) CH (2) PPh (2)) Co2 (CO) 4 (micro,eta-PhC [triple bond] CP (t-Bu) 2)] 4a underwent a partial oxidation. |
82(1,1,1,2) | Details |
| 12924903 | Maspero A, Kani I, Mohamed AA, Omary MA, Staples RJ, Fackler JP Jr: Syntheses and structures of dinuclear gold (I) dithiophosphonate complexes and the reaction of the dithiophosphonate complexes with phosphines: diverse coordination types. Inorg Chem. 2003 Aug 25;42(17):5311-9. The dinuclear gold (I) dithiophosphonate complex, [Au (2)(dtp)(2)] (1), where dtp = [S (2) P (R)(OR')](-) with R = p-C (6) H (4) OCH (3); R'= c-C (5) H (9), has been synthesized and its reaction studied with the phosphine ligands PPh (3) and Ph (2) P (CH (2))(n) PPh (2) (n = 1-4). |
82(1,1,1,2) | Details |
| 12889975 | Crumpton-Bregel DM, Goldberg KI: Mechanisms of C-C and C-H reductive eliminations from octahedral Pt (IV): reaction via five-coordinate intermediates or direct elimination?. J Am Chem Soc. 2003 Aug 6;125(31):9442-56. The Pt (IV) complexes P (2) PtMe (3) R [P (2) = dppe (PPh (2)(CH (2))(2) PPh (2)), dppbz (o-PPh (2)(C (6) H (4)) PPh (2)); R = Me, H] undergo reductive elimination reactions to form carbon-carbon or carbon- bonds. For C-C reductive elimination, the evidence supports a mechanism of initial phosphine chelate opening followed by C-C coupling from the resulting five-coordinate intermediate. |
1(0,0,0,1) | Details |
| 17637994 | Poorters L, Armspach D, Matt D, Toupet L: alpha-TEPHOS: a cyclodextrin-derived tetraphosphine for multiple metal binding. Dalton Trans. 2007 Aug 7;(29):3195-202. Epub 2007 May 24. The tetraphosphine 6 (A),6 (B),6 (D),6 (E)-tetradeoxy-6 (A),6 (B),6 (D),6 (E)-tetra (diphenylphosphiny l)-2 (A),2 (B),2 (C),2 (D),2 (E),2 (F),3 (A),3 (B),3 (C),3 (D),3 (E),3 (F),6 (C),6 (F)-t etradeca-O-methyl-alpha-cyclodextrin (alpha-TEPHOS) has been prepared in high yield by reacting 6 (A),6 (B),6 (D),6 (E)-tetra-O-methylsulfonyl-2 (A),2 (B),2 (C),2 (D), 2 (E),2 (F),3 (A),3 (B),3 (C),3 (D),3 (E),3 (F),6 (C),6 (F)-tetradeca-O-methyl-alpha -cyclodextrin with excess PPh (2) Li. The product was purified in its BH (3)-protected form. alpha-TEPHOS is the first optically active tetraphosphine in which the four phosphine units are tethered to a cavity-shaped scaffold. |
1(0,0,0,1) | Details |
| 20017482 | Shen Z, Jordan RF: Self-assembled tetranuclear palladium catalysts that produce high molecular weight linear polyethylene. J Am Chem Soc. 2010 Jan 13;132(1):52-3. The phosphine-bis-arenesulfonate ligand PPh (2-SO (3) Li-4-Me-Ph)(2) (Li (2)[OPO]) coordinates as a kappa (2)-P,O chelator in Li [(Li-OPO) PdMe (Cl)] (2a) and (Li-OPO) PdMe (L) (L = (2b); MeOH (2d); 4-(5-nonyl) (py', 3)). 2a reacts with AgPF (6) to form {(Li-OPO) PdMe}(n) (2c). |
81(1,1,1,1) | Details |
| 18698441 | Jones C, Mills DP, Rose RP, Stasch A: Synthesis and structural characterisation of group 10 metal (II) gallyl complexes: analogies with platinum diboration catalysts?. Dalton Trans. 2008 Sep 7;(33):4395-408. Epub 2008 Jul 3. Reactions of the anionic gallium (i) heterocycle, [:Ga{[N (Ar) C (H)](2)}](-) (Ar = C (6) H (3) Pr (i)(2)-2,6), with a variety of mono- and bidentate phosphine, tmeda and 1,5-cyclooctadiene (COD) complexes of group 10 metal dichlorides are reported. In most cases, salt elimination occurs, affording either mono (gallyl) complexes, trans-[MCl{Ga{[N (Ar) C (H)](2)}}(PEt (3))(2)] (M = Ni or Pd) and cis-[PtCl{Ga{[N (Ar) C (H)](2)}}(L)] (L = R (2) PCH (2) CH (2) PR (2), R = Ph (dppe) or cyclohexyl (dcpe)), or bis (gallyl) complexes, trans-[M{Ga{[N (Ar) C (H)](2)}}(2)(PEt (3))(2)] (M = Ni, Pd or Pt), cis-[Pt{Ga{[N (Ar) C (H)](2)}}(2)(PEt (3))(2)], cis-[M{Ga{[N (Ar) C (H)](2)}}(2)(L)] (M = Ni, Pd or Pt; L = dppe, Ph (2) CH (2) PPh (2) (dppm), tmeda or COD). |
1(0,0,0,1) | Details |
| 15913366 | Semmelhack MF, Chlenov A, Ho DM: Accelerated arene ligand exchange in the (Arene) Cr (CO) 2L series. J Am Chem Soc. 2005 Jun 1;127(21):7759-73. The system evaluated here employs derivatives of tris (pyrrolyl) phosphine as L. A series of 2-L'-substituted pyrroles was prepared, where the substituents include: L' = -SMe, -CH (2) SMe, -SPh, -CH (2) SPh, -SCF (3), -S-tBu, -CO (2) Me, -CONMe (2), -2-pyridinyl, and -PPh (2). |
1(0,0,0,1) | Details |
| 15845013 | Curran DP, Wang X, Zhang Q: Light, medium, and heavy fluorous triarylphosphines exhibit comparable reactivities to triphenylphosphine in typical reactions of triarylphosphines. J Org Chem. 2005 Apr 29;70(9):3716-9. A light fluorous phosphine [(p-C (8) F (17)(CH (2))(2) C (6) H (4)) PPh (2)] outperforms a commercially available resin-bound phosphine in a competitive benzylation experiment by a factor of about 4. |
81(1,1,1,1) | Details |
| 20023970 | Chisholm DM, Oliver AG, McIndoe JS: Mono-alkylated bisphosphines as dopants for ESI-MS analysis of catalytic reactions. Dalton Trans. 2010 Jan 14;(2):364-73. Epub 2009 Oct 14. Bisphosphines Ph (2) P (CH (2))(n) PPh (2) (n = 1, 2, 4, 6) may be easily monobenzylated to generate cationic phosphine/phosphonium ligands [Ph (2) P (CH (2))(n) PPh (2) CH (2) Ph](+). |
81(1,1,1,1) | Details |
| 16357969 | Meyer C, Scherer M, Schonberg H, Ruegger H, Loss S, Gramlich V, Grutzmacher H: Coordination chemistry of phosphanyl amino acids: solid state and solution structures of neutral and cationic rhodium complexes. Dalton Trans. 2006 Jan 7;(1):137-48. Epub 2005 Nov 29. phosphide or arsenide complexes, [Cu (EPh (2))(neo)] (E = P, As, neo = 2,9-dimethyl-1,10-phenanthroline; trivial name: neocuprine) react selectively with the N-protected brominated serine derivatives, 2-(S)-(alkoxycarbonylamino)-3-bromomethylpropionates ((ROCO) SerBr, : R = PhCH (2), : tBu, : Me) to give the corresponding phosphanylated or arsanylated amino acids, (ROCO) SerPhos (: Phos = PPh (2)) and (Z) SerArs (Ars = AsPh (2), Z = PhCH (2) OCO). |
1(0,0,0,1) | Details |
| 15852111 | Ortin Y, Lugan N, Mathieu R: Subtle reactivity patterns of non-heteroatom-substituted alkynyl carbene complexes in the presence of probes. Dalton Trans. 2005 May 5;(9):1620-36. Epub 2005 Apr 1. In the presence of PPh3, complexes act as a Michael acceptor to afford the zwitterionic sigma-allenylphosphonium complexes (eta5-MeC5H4)(CO) 2MnC (R)=C=C (PPh3) R' (5) resulting from nucleophilic attack by the phosphine on the remote alkynyl carbon atom. |
0(0,0,0,0) | Details |
| 14686848 | Blake CJ, Cook VC, Keniry MA, Kitto HJ, Rae AD, Swiegers GF, Willis AC, Zank J, Wild SB: Diastereoselectivity and molecular recognition in the self-assembly of double-stranded dinuclear metal complexes of the type [M2 [(R,S)-tetraphos] 2](PF6) 2 (M = Ag and Au). Inorg Chem. 2003 Dec 29;42(26):8709-15. The ligand (R,S)-Ph (2) PCH (2) CH (2) P (Ph) CH (2) CH (2) P (Ph) CH (2) CH (2) PPh (2), (R,S)-tetraphos, combines with silver (I) and gold (I) ions in the presence of hexafluorophosphate to diastereoselectively self-assemble the head-to-head (H,H) diastereomers of the double-stranded, dinuclear metal complexes [M (2)[(R,S)-tetraphos](2)](PF (6))(2) in which the two chiral metal centers in the complexes have M (R end of phosphine) and P (S end of phosphine) configurations. |
32(0,1,1,2) | Details |
| 15291581 | Jaska CA, Manners I: Heterogeneous or homogeneous catalysis? Mechanistic studies of the rhodium-catalyzed dehydrocoupling of amine-borane and phosphine-borane adducts. J Am Chem Soc. 2004 Aug 11;126(31):9776-85. In depth, comparative studies on the catalytic dehydrocoupling of the amine-borane adduct Me (2) NH.BH (3) (to form [Me (2) N-BH (2)](2)) and the phosphine-borane adduct Ph (2) PH.BH (3) (to form Ph (2) PH-BH (2)-PPh (2)-BH (3)) with a variety of Rh (pre) catalysts such as [[Rh (1,5-cod)(micro-Cl)](2)], Rh/Al (2) O (3), Rh (colloid)/[Oct (4) N] Cl, and [Rh (1,5-cod)(2)] OTf have been performed in order to determine whether the dehydrocoupling proceeds by a homogeneous or heterogeneous mechanism. |
31(0,1,1,1) | Details |
| 19303144 | Song LC, Gai B, Wang HT, Hu QM: Synthesis, characterization and electrocatalysis of diiron propanediselenolate derivatives as the active site models of [FeFe]-hydrogenases. J Inorg Biochem. 2009 May;103(5):805-12. Epub 2009 Feb 15. Further reaction of 1 with PPh (3) or PPh (2) H in the presence of Me (3) NO in MeCN at room temperature afforded the phosphine-monosubstituted model compounds [micro-Se (CH (2))(3) Se-micro] Fe (2)(CO)(5)(L) (2, L=PPh (3); 3, L=PPh (2) H) in 76% and 68% yields, respectively. |
0(0,0,0,0) | Details |
| 19222213 | Sloan ME, Clark TJ, Manners I: Homogeneous Catalytic Dehydrogenation/Dehydrocoupling of Amine-Borane Adducts by the Rh (I) Wilkinson's Complex Analogue RhCl (PHCy (2))(3) (Cy = cyclohexyl). Inorg Chem. 2009 Feb 17. The Rh (I) complex 1 (but not the Ir (I) analogue 2) was also found to be active for the catalytic dehydrocoupling of the phosphine-borane adduct Ph (2) PH.BH (3) (14) at 60-90 degrees C to afford linear dimer Ph (2) PH-BH (2)-PPh (2)-BH (3) (15). |
0(0,0,0,0) | Details |
| 16028936 | Schuh W, Braunstein P, Benard M, Rohmer MM, Welter R: Metal "capture" by a heterotrimetalloligand, heterometallic d (10)-d (10) interactions, and unexpected iron-to-platinum silyl ligand migration: a combined experimental and theoretical study. J Am Chem Soc. 2005 Jul 27;127(29):10250-8. The heterotrinuclear chain complex Hg [Fe{Si (OMe)(3)}(CO)(3)(dppm-P)](2) (dppm = Ph (2) PCH (2) PPh (2)) 1 which has a transoid arrangement of the phosphine donors was used as a versatile chelating metallodiphosphine ligand owing to the easy rotation of its metal core about the Fe-Hg sigma-bonds. |
31(0,1,1,1) | Details |
| 19790213 | Di Credico B, Fabrizi de Biani F, Gonsalvi L, Guerri A, Ienco A, Laschi F, Peruzzini M, Reginato G, Rossin A, Zanello P: Cyclopentadienyl ruthenium (II) complexes with bridging alkynylphosphine ligands: synthesis and electrochemical studies. Chemistry. 2009 Nov 9;15(44):11985-98. The reaction of [CpRuCl (PPh (3))(2)] (Cp = cyclopentadienyl) and [CpRuCl (dppe)] (dppe = Ph (2) PCH (2) CH (2) PPh (2)) with bis- and tris-phosphine ligands 1,4-(Ph (2) PC [triple bond] C)(2) C (6) H (4) (1) and 1,3,5-(Ph (2) PC [triple bond] C)(3) C (6) H (3) (2), prepared by Ni-catalysed cross-coupling reactions between terminal alkynes and diphenylchlorophosphine, has been investigated. |
31(0,1,1,1) | Details |
| 14750856 | Han MJ, Wang D, Hao JM, Wan LJ, Zeng QD, Fan QH, Bai CL: Absolute configuration of monodentate phosphine ligand enantiomers on Cu (111). Anal Chem. 2004 Feb 1;76(3):627-31. The absolute configuration of 1-(2-diphenyphosphino-1-naphthyl) isoquinoline enantiomers with axial chirality was discriminated directly by the "marker" group, PPh (2) substitutes. |
2(0,0,0,2) | Details |
| 19885535 | Garralda MA, Hernandez R, Pinilla E, Torres MR, Zarandona M: Selective formation of cis-diacyl, cis-PPh (2) R rhodium (III) complexes by the reaction of rhodium (III) cis-diacyl, trans-PPh (2) R complexes with aliphatic diamines. Dalton Trans. 2009 Nov 28;(44):9860-9. Epub 2009 Sep 30. More basic amino groups prefer positions trans to an acyl group while less basic amino groups are trans to a phosphine group. |
2(0,0,0,2) | Details |
| 19921059 | Dai FR, Li B, Shi LX, Zhang LY, Chen ZN: Photochromic and electrochromic properties of oxo-centred triruthenium compounds with a dithienylethene bis (phosphine) ligand. Dalton Trans. 2009 Dec 14;(46):10244-9. Epub 2009 Sep 9. The reaction of 1,2-bis (5-(diphenylphosphino)-2-methylthien-3-yl) cyclopentene (PPh (2)-DTE-PPh (2)) with the triruthenium cluster precursor [Ru (3) O (OAc)(6)(py)(2)(CH (3) OH)](PF (6)) (1) gave monomeric or dimeric derivatives [Ru (3) O (OAc)(6)(py)(2){PPh (2)-DTE-PPh (2)}](PF (6)) ([2] PF (6)) and [{Ru (3) O (OAc)(6)(py)(2)}(2){mu-PPh (2)-DTE-PPh (2)}](PF (6))(2) ([3] PF (6)). |
2(0,0,0,2) | Details |
| 12919015 | Takaki K, Koshoji G, Komeyama K, Takeda M, Shishido T, Kitani A, Takehira K: Intermolecular hydrophosphination of alkynes and related carbon [bond] carbon multiple bonds catalyzed by organoytterbiums. J Org Chem. 2003 Aug 22;68(17):6554-65. Intermolecular hydrophosphination of alkynes with diphenylphosphine is catalyzed by a Yb [bond] imine complex, [Yb (eta (2)-Ph (2) CNPh)(hmpa)(3)], to give alkenylphosphines and phosphine oxides after oxidative workup in good yields under mild conditions. Instead, the reaction takes place through insertion of alkynes to a Yb [bond] PPh (2) species, followed by protonation. |
1(0,0,0,1) | Details |
| 16969780 | Lee CC, Ke WC, Chan KT, Lai CL, Hu CH, Lee HM: (II) complexes of bidentate N-heterocyclic carbene/phosphine ligands: efficient catalysts for Suzuki coupling of aryl chlorides. Chemistry. 2007;13(2):582-91. Unlike the previously reported [NiCl (2)(dppe)] (dppe=1,2-bis (diphenylphosphino) ethane), 2 a can effectively catalyze the cross-coupling reaction without the need for a catalytic amount of PPh (3), and this suggests that the PPh (2) functionality of hybrid NHC ligand L can partially take on the role of free PPh (3). |
1(0,0,0,1) | Details |
| 17009375 | Crespo O, Gimeno MC, Laguna A, Larraz C, Villacampa MD: Highly luminescent gold (I)-silver (I) and gold (I)- (I) chalcogenide clusters. Chemistry. 2007;13(1):235-46. The reactions of [AuClL] with Ag (2) O, where L represents the heterofunctional ligands PPh (2) py and PPh (2) CH (2) CH (2) py, give the trigoldoxonium complexes [O (AuL)(3)] BF (4). These trinuclear species react with Ag (OTf) or [Cu (NCMe)(4)] PF (6) to give different results, depending on the phosphine and the metal. |
1(0,0,0,1) | Details |
| 19728718 | Li X, Nishiura M, Hu L, Mori K, Hou Z: Alternating and random copolymerization of isoprene and ethylene catalyzed by cationic half-sandwich scandium alkyls. J Am Chem Soc. 2009 Sep 30;131(38):13870-82. The analogous half-sandwich complexes having a heteroatom-containing side arm, (C (5) Me (4) R) Sc (CH (2) SiMe (3))(2) (R = CH (2) CH (2) PPh (2) (6), C (6) H (4) OMe-omicron (7)), were obtained by the one-pot metathetical reactions of ScCl (3)(THF)(3) with 1 equiv of the salts of the ligands and 2 equiv of LiCH (2) SiMe (3). The ether side arm coordinated complex 7 preferred trans-1,4-polyisoprene formation (60-79%), whereas the phosphine analogue 6 showed high cis-1,4 selectivity (84-90%) under the same conditions. |
1(0,0,0,1) | Details |
| 20333340 | Flower KR, McGown AT, Miles PJ, Pritchard RG, Warren JE: Isolation of 1,4-Li (2)-C (6) H (4) and its reaction with [(Ph (3) P) AuCl]. Dalton Trans. 2010 Apr 14;39(14):3509-20. Epub 2010 Mar 2. Subsequent treatment of with 2.5 molar equivalents of PPh (2) Me, PPhMe (2) or PMe (3) affords the PPh (3) substituted compounds [1,4-(LAu)(2)-C (6) H (4)] (L = PPh (2) Me , PPhMe (2), PMe (3)) in essentially quantitative yields. The solid state structures observed for are dictated by non-conventional bonding and the packing requirements of the phosphine ligands. |
1(0,0,0,1) | Details |
| 14753832 | Jaska CA, Lough AJ, Manners I: Linear hybrid aminoborane/phosphinoborane chains: synthesis, -hydride interactions, and thermolysis behavior. Inorg Chem. 2004 Feb 9;43(3):1090-9. The reaction of the lithiated phosphine-borane adducts Li [PPhR.BH (3)] or Li [CH (2)-PR (2).BH (3)] with Me (2) NH.BH (2) Cl afforded the hybrid linear species Me (2) NH-BH (2)-PPhR-BH (3) (1, R = Ph; 2, R = H) or Me (2) NH-BH (2)-CH (2)-PR (2)-BH (3) (3, R = Ph; 4, R = Me). Chain cleavage reactions were observed for 1 and 2 upon thermolysis at 130 degrees C to afford species such as Me (2) NH.BH (3), [Me (2) N-BH (2)](2), PhPRH.BH (3) (R = Ph, H), PhPRH (R = Ph, H), Ph (2) PH-BH (2)-PPh (2)-BH (3), and also the low molecular weight polyphosphinoborane [PhPH-BH (2)](n) (M (w) approximately 5000). |
1(0,0,0,1) | Details |
| 19436900 | Nixon TD, Dingwall LD, Lynam JM, Whitwood AC: Self-assembly of a bonded framework from a gold phosphine complex with a pendant group. Chem Commun. 2009 May 28;(20):2890-2. Epub 2009 Apr 6. The easily prepared complex AuCl (PPh (2) Ur) (Ur = self-assembles in the solid state to form crystals containing solvent-accessible channels, the structure remains crystalline even after removal and re-addition of solvent. |
1(0,0,0,1) | Details |
| 19093856 | Imaji M, Tanabe Y, Mutoh Y, Ishii Y: Core expansion reactions of cyanamido/carbodiimido-bridged polynuclear iridium complexes. Inorg Chem. 2009 Jan 19;48(2):773-80. Core expansion reactions of di- and tetrairidium complexes [Cp*Ir (mu (2)-NCN-N,N)](2) (1; Cp* = eta (5)-C (5) Me (5)), [Cp*Ir (mu (3)-NCN-N,N,N)](4) (2), and phosphine derivatives of 1 have been investigated, and it has been revealed that cyanamido ligands in these complexes can change their coordination modes flexibly on reactions with a second transition metal complex. Diphosphine derivative of 1, [{Cp*Ir (mu (2)-NCN)}(2)(mu-dppm)] (4; dppm = Ph (2) PCH (2) PPh (2)), behaves differently on reactions with [PdCl (eta (3)-C (3) H (5))](2) and [MCl (cod)](2) (cod = cycloocta-1,5-diene) to form the NCN-bridged Ir (2) (M = Pd, Rh, Ir) tetranuclear complexes [(Cp*Ir)(2)(mu (3)-NCN-N,N,N')(2){PdCl (eta (3)-C (3) H (5))}(2)(mu-dppm)] (9) and [(Cp*Ir)(2)(mu (3)-NCN-N,N,N')(2){MCl (cod)}(2)(mu-dppm)] (11a, M = Rh; 11b, M = Ir), respectively. |
1(0,0,0,1) | Details |
| 15809987 | Hua R, Onozawa SY, Tanaka M: Rhodium-catalyzed nondecarbonylative addition reaction of ClCOCOOC2H5 to alkynes. Chemistry. 2005 Jun 6;11(12):3621-30. Addition of ethoxalyl (ClCOCOOEt) to terminal alkynes at 60 degrees C in the presence of a rhodium (I)-phosphine complex catalyst chosen from a wide range affords 4-chloro-2-oxo-3-alkenoates regio- and stereoselectively. The oxidative addition of ethoxalyl to [RhCl (CO)(PR (3))(2)] proceeds readily at 60 degrees C or room temperature and gives [RhCl (2)(COCOOEt)(CO)(PR (3))(2)] (PR (3) = PPh (2) Me, PPhMe (2), PMe (3)) complexes in high yields. |
1(0,0,0,1) | Details |
| 17091519 | Wei CH, Wu CE, Huang YL, Kultyshev RG, Hong FE: Experimental and DFT study of the tautomeric behavior of -containing secondary phosphine oxides. Chemistry. 2007;13(5):1583-93. New -containing secondary phosphine oxides [(mu-PPh (2) CH (2) PPh (2)) Co (2)(CO)(4){mu,eta-PhC [triple chemical bond] CP (==O)(H)(R)}] (8 a: R=tBu; 8 b: R=Ph) were prepared by reaction of secondary phosphine oxides PhC [triple chemical bond] CP- (==O)(H)(R) (6 a: R=tBu; 6 b: R=Ph) with dppm-bridged dicobalt complex [(mu-PPh (2) CH (2) PPh (2)) Co (2)(CO)(6)] (2). |
162(2,2,2,2) | Details |
| 16482349 | Bai G, Wei P, Das AK, Stephan DW: P-H and P-P bond activation by Ni (I) and Fe (I) beta-diketiminato-complexes. Dalton Trans. 2006 Mar 7;(9):1141-6. Epub 2005 Dec 14. Reactions of ((NacNac) Ni) 2 (mu-eta3-eta3-C6H5Me) (NacNac = HC (CMeNC6H3 (i-Pr) 2) 2) with PH2Ph or PHPh2 proceeds in a facile manner to afford the Ni (I)-phosphine adducts (NacNac) Ni (PH2Ph) and (NacNac) Ni (PHPh2) , respectively. The Ni (II) di-phosphosphine bridged compound [((NacNac) Ni) 2 (mu4-(PPh) 2)] was prepared via reaction of ((NacNac) Ni) 2 (mu-eta3-eta3-C6H5Me) with P5Ph5. |
1(0,0,0,1) | Details |
| 12833291 | Engeldinger E, Armspach D, Matt D, Jones PG: Cyclodextrin phosphanes as first and second coordination sphere cavitands. Chemistry. 2003 Jul 7;9(13):3091-105. The binding properties of two alpha-cyclodextrins, each containing two C (5)-linked "CH (2) PPh (2)" units, L 1 (A,D-substituted) and L 2 (A,C-substituted), have been investigated. |
1(0,0,0,1) | Details |
| 20028110 | Lagaditis PO, Mikhailine AA, Lough AJ, Morris RH: Template synthesis of iron (II) complexes containing tridentate P-N-S, P-N-P, P-N-N, and tetradentate P-N-N-P ligands. Inorg Chem. 2010 Feb 1;49(3):1094-102. A series of mer-tridentate iron (II) complexes bearing P-N-S (3), P-N-P (4), and P-N-N (5) ligands have been prepared via the metal template effect in one pot involving air-stable phosphonium dimers [cyclo-(-PPh (2) CH (2) C (OH) H-)(2)](Br)(2) (1) and [cyclo-(-PCy (2) CH (2) C (OH) H-)(2)](Br)(2) (2), KOtBu, [Fe (H (2) O)(6)][BF (4)](2) and 2-aminothiolphenol (for 3), 2-(diphenylphosphino) ethylamine (for 4), and 2-(aminomethyl) (for 5). Complexes [Fe{PR (2) CH (2) CH=NCH (2)(2-C (5) H (4) N)}(2)](BPh (4))(2) (5) are bis-tridentate iron (II) complexes with pyridyl donors trans to the phosphine donors. |
2(0,0,0,2) | Details |
| 17339999 | Bowen LE, Haddow MF, Orpen AG, Wass DF: One electron oxidation of N,N-bis (diarylphosphino) amine and bis (diarylphosphino) complexes relevant to ethene trimerisation and tetramerisation. Dalton Trans. 2007 Mar 21;(11):1160-8. Epub 2007 Feb 9. Complexes of the type [(diphosphine) Cr (CO)(4)] (diphosphine = Ph (2) PN (iPr) PPh (2), Ar (2) PN (Me) PAr (2) or Ar (2) PCH (2) PAr (2) (Ar = 2-C (6) H (4)(MeO)) have been synthesised. In the solid state, these complexes show tight phosphine bite angles in the range 67.82 (4) degrees to 71.52 (5) degrees and the atom in N,N-bis (diarylphophino) amine ligands adopts an almost planar (sp (2)) geometry. |
1(0,0,0,1) | Details |
| 15285668 | Chan EY, Zhang QF, Sau YK, Lo SM, Sung HH, Williams ID, Haynes RK, Leung WH: Chiral bisphosphinite metalloligands derived from a P-chiral secondary phosphine oxide. Inorg Chem. 2004 Aug 9;43(16):4921-6. Reaction of 2 with Na [S (2) CNEt (2)] or K [N (PPh (2) S)(2)] afforded Pd [(1)(2) H](S (2) CNEt (2)) (3) or Pd [(1)(2) H)[N (PPh (2) S)(2)] (4), respectively. |
1(0,0,0,1) | Details |
| 18767796 | Franken A, Hodson BE, McGrath TD, Stone FG: Formation of intramolecular rings in ferramonocarbollide complexes. . Inorg Chem. 2008 Oct 6;47(19):8788-97. Epub 2008 Sep 4. Deprotonation (NaH) of the phosphine ligand in 2a, with subsequent addition of [IrCl (CO)(PPh 3) 2] and Tl [PF 6], yields the neutral, zwitterionic complex [6,6,6-(CO) 3-4,7-mu-{Ir (H)(CO)(PPh 3) 2PPh 2}- closo-6,1-FeCB 8H 7] ( 3), which contains a B-P-Ir- B ring. Addition of [Co 2 (CO) 8] to CH 2Cl 2 solutions of the latter gives [6,6,6-(CO) 3-7-(PPh 2-{(mu-eta (2):eta (2)-CCMe) Co 2 (CO) 6})- closo-6,1-FeCB 8H 8] ( 5), which contains a {C 2Co 2} tetrahedron. |
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| 18682866 | Lopez-Serrano J, Duckett SB, Dunne JP, Godard C, Whitwood AC: Palladium catalysed alkyne hydrogenation and oligomerisation: a parahydrogen based NMR investigation. Dalton Trans. 2008 Aug 28;(32):4270-81. Epub 2008 Jun 25. The role phosphine ligands play in the palladium (ii)-bis-phosphine-hydride cation catalysed hydrogenation of diphenylacetylene is explored through a PHIP (parahydrogen induced polarization) NMR study. The precursors Pd (LL')(OTf)(2) (1a-e) [LL' = dcpe (PCy (2) CH (2) CH (2) PCy (2)), dppe, dppm, dppp, cppe (PCy (2) CH (2) CH (2) PPh (2))] are used. |
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