Protein Information

Name LH 2
Synonyms Homeobox protein LH 2; LH 2; LH2; LHX 2; LHX2; LIM homeobox 2; LIM/homeobox protein Lhx2; Lim homeo box gene 2…

Compound Information

Name butylamine
CAS 2-butanamine

Reference List

PubMed Abstract RScore(About this table)
18368146 Sinha S, Srivastava AK, Tripathi CM, Pandey OP, Sengupta SK: Synthesis, Spectroscopic, and Antimicrobial Studies of Binuclear Metallocene (M = Ti, Zr, or Hf) Derivatives of Bis (mercaptoazoles). Bioinorg Chem Appl. 2007:87918.

The reactions of (eta (5) - C (5) H (5))(2) MCl (2) (M = Ti, Zr, or Hf) with mercaptoazoles (LH (2)), namely, bis (mercaptotriazoles), bis (mercap- tooxadiazoles), and bis (mercaptothiadiazoles) in 2 : 1 molar ratio, respectively, have been studied in dry tetrahydrofuran in the presence of n-butylamine and the binuclear complexes of the type [{(eta - C (5) H (5))(2) M}(2)(L)] (M = Ti/Zr/Hf) are obtained.
31(0,1,1,1) Details
16471998 Hlavinka ML, McNevin MJ, Shoemaker R, Hagadorn JR: Dizinc alkoxides and amides supported by binucleating bis (amidoamine) ligands. Inorg Chem. 2006 Feb 20;45(4):1815-22.

The previously reported dinuclear organozinc species (Me) LZn2Ph2 (9) reacts with 1 equiv of tert-butylamine to form the protonolysis product (Me) LZn2 (Ph)(NH (t) Bu) (10) in 66% isolated yield.
Reaction of N,N'-bis (2-dimethylaminoethyl) dibenzofuran-4,6-diamine ((Me) LH (2)) with 2 equiv of EtZn (O (i) Pr) forms the dizinc bis (alkoxide) (Me) LZn2 (O (i) Pr) 2 (1), which was isolated in 76% yield.
1(0,0,0,1) Details