Protein Information

Name C15
Synonyms BM 004; PLAC 8; PLAC8; C15; C15 protein; Placenta specific gene 8; Placenta specific gene 8 protein; Protein C15…

Compound Information

Name sodium azide
CAS sodium azide

Reference List

PubMed Abstract RScore(About this table)
19746943 Rogers EW, Molinski TF: (+)-Zwittermicin A. J Org Chem. 2009 Oct 16;74(20):7660-4.

A short, enantioselective synthesis of the C9-C15 portion of (+)-zwittermicin A is reported that exploits directional functionalization of the known hepta-2,5-diyne-1,7-diol by partial reduction of the two triple bonds followed by Sharpless asymmetric epoxidation and boron-directed double ring-opening with sodium azide under Miyashita conditions.
32(0,1,1,2) Details