Protein Information

Name CS 2
Synonyms CS 2; CSH 1; CSH1; Choriomammotropin; Placental lactogen; CSB; CSH 2; CSH2…

Compound Information

Name OCH
CAS 2,3,4,4,5,5,6,6-octachloro-2-cyclohexen-1-one

Reference List

PubMed Abstract RScore(About this table)
20066232 Yeguas V, Campomanes P, Lopez R: Reactivity of a rhenium hydroxo-carbonyl complex toward carbon disulfide: insights from theory. Dalton Trans. 2010 Jan 21;39(3):874-82. Epub 2009 Nov 20.


Besides, our findings permit to explain the assignment of the solution color change to the formation of [Re (SH)(CO)(3)(bipy)] when mixed CS (2) with [Re (OH)(CO)(3)(bipy)].
2(0,0,0,2) Details
20163106 Semeniuc RF, Reamer TJ, Blitz JP, Wheeler KA, Smith MD: Functionalized O-alkyldithiocarbonates: a new class of ligands designed for luminescent heterometallic materials. Inorg Chem. 2010 Mar 15;49(6):2624-9.

The new ligand 4-PyCH (2) OCS (2) Na, that combines two different donor groups in one molecule (a soft -CS (2)(-) group and a hard pyridine moiety), has been synthesized.
Using a Ni (II) dithiophosphonate linker, the heterometallic {[CH (3) OCH (2) CH (2) OP (An) S (2)](2) Ni}[4-PyCH (2) OCS (2) Re (bipy)(CO)(3)](2) complex is obtained, through the coordination of two pyridine groups to the Ni (II) center.
1(0,0,0,1) Details
12506373 Song LC, Fan HT, Hu QM, Yang ZY, Sun Y, Gong FH: Formation and chemical reactivities of a new type of double-butterfly [[Fe2 (mu-CO)(CO) 6] 2 (mu-SZS-mu)] 2-: synthetic and structural studies on novel linear and macrocyclic butterfly Fe/E (E=S, Se) cluster complexes. Chemistry. 2003 Jan 3;9(1):170-80.


For instance, while reactions of 3 with PhC (O) Cl and Ph (2) PCl give linear clusters [[Fe (2)(mu-PhCO)(CO)(6)](2)(mu-SZS-mu)] (4 a,b: Z=CH (2)(CH (2) OCH (2))(2,3) CH (2)) and [[Fe (2)(mu-Ph (2) P)(CO)(6)](2)(mu-SZS-mu)] (5 a,b: Z=CH (2)(CH (2) OCH (2))(2,3) CH (2)), reactions with CS (2) followed by treatment with monohalides RX or dihalides X-Y-X give both linear clusters [[Fe (2)(mu-RCS (2))(CO)(6)](2)(mu-SZS-mu)] (6 a-e: Z=CH (2)(CH (2) OCH (2))(1,2) CH (2); R=Me, PhCH (2), FeCp (CO)(2)) and macrocyclic clusters [[Fe (2)(CO)(6)](2)(mu-SZS-mu)(mu-CS (2) YCS (2)-mu)] (7 a-e: Z=(CH (2))(4), CH (2)(CH (2) OCH (2))(1-3) CH (2); Y=(CH (2))(2-4), 1,3,5-Me (CH (2))(2) C (6) H (3), 1,4-(CH (2))(2) C (6) H (4)).
1(0,0,0,1) Details
12203319 Cameron TS, Decken A, Dionne I, Fang M, Krossing I, Passmore J: Approaching the gas-phase structures of [AgS8]+ and [AgS16]+ in the solid state. Chemistry. 2002 Aug 2;8(15):3386-401.


Upon treating elemental sulfur with [AgSbF (6)], [AgAl (hfip)(4)], [AgAl (pftb)(4)] (hfip=OCH (CF (3))(2), pftb =OC (CF (3))(3)) the compounds [Ag (S (8))(2)][SbF (6)] (1), [AgS (8)][Al (hfip)(4)] (2), and [Ag (S (8))(2)](+)[[Al (pftb)(4)](-) (3) formed in SO (2) (1), CS (2) (2), or CH (2) Cl (2) (3).
1(0,0,0,1) Details