Protein Information

Name PPh 2
Synonyms PPH 2; PPH2; primary pulmonary hypertension 2; primary pulmonary hypertension 2s

Compound Information

Name OCH
CAS 2,3,4,4,5,5,6,6-octachloro-2-cyclohexen-1-one

Reference List

PubMed Abstract RScore(About this table)
20148211 Huo XK, Su G, Jin GX: Neutral and zwitterionic half-sandwich Ir, Rh complexes supported by P,S-substituted o-carboranyl ligands: Synthesis, characterization and reactivity. Dalton Trans. 2010 Feb 28;39(8):1954-61. Epub 2010 Jan 5.

The 18-electron neutral closo-carborane complexes Cp*M (Cl)(1-PPh (2)-2-S-1,2-C (2) B (10) H (10)) (M = Ir (), Rh ()) can be easily deboronated to result in the formation of reactive 16-electron zwitterionic nido-carborane complexes [Cp*M (3-OCH (3)-7-PPh (2)-8-S-7,8-C (2) B (9) H (9))] (M = Ir (), Rh ()).
112(1,2,2,2) Details
12924903 Maspero A, Kani I, Mohamed AA, Omary MA, Staples RJ, Fackler JP Jr: Syntheses and structures of dinuclear gold (I) dithiophosphonate complexes and the reaction of the dithiophosphonate complexes with phosphines: diverse coordination types. Inorg Chem. 2003 Aug 25;42(17):5311-9.


The dinuclear gold (I) dithiophosphonate complex, [Au (2)(dtp)(2)] (1), where dtp = [S (2) P (R)(OR')](-) with R = p-C (6) H (4) OCH (3); R'= c-C (5) H (9), has been synthesized and its reaction studied with the phosphine ligands PPh (3) and Ph (2) P (CH (2))(n) PPh (2) (n = 1-4).
2(0,0,0,2) Details
15154812 Wei QH, Yin GQ, Zhang LY, Shi LX, Mao ZW, Chen ZN: Luminescent Ag i-Cu i heterometallic hexa-, octa-, and hexadecanuclear alkynyl complexes. Inorg Chem. 2004 May 31;43(11):3484-91.


The heterooctanuclear complexes 3-6 exhibit a waterwheel-like structure that can be regarded as two Ag (3) Cu (CCC (6) H (5))(3) components put together by three bridging Ph (2) PCH (2) PPh (2) ligands.
1(0,0,0,1) Details
11666327 Wang D, Angelici RJ: Effects of Cyclopentadienyl and Phosphine Ligands on the Basicities and Nucleophilicities of Cp'Ir (CO)(PR (3)) Complexes. Inorg Chem. 1996 Feb 28;35(5):1321-1331.


Basicities of the series of complexes CpIr (CO)(PR (3)) [PR (3) = P (p-C (6) H (4) CF (3))(3), P (p-C (6) H (4) F)(3), P (p-C (6) H (4) Cl)(3), PPh (3), P (p-C (6) H (4) CH (3))(3), P (p-C (6) H (4) OCH (3))(3), PPh (2) Me, PPhMe (2), PMe (3), PEt (3), PCy (3)] have been measured by the heat evolved (DeltaH (HM)) when the complex is protonated by CF (3) SO (3) H in 1,2-dichloroethane (DCE) at 25.0 degrees C.
1(0,0,0,1) Details
11670732 Bendix J, Bogevig A: Synthesis and Characterization of a Stable trans-Dioxo Tungsten (IV) Complex and Series of Mono-Oxo Molybdenum (IV) and Tungsten (IV) Complexes. Inorg Chem. 1998 Nov 16;37(23):5992-6001.


trans-[W (O)(F)(dppe)(2)](BF (4)) (dppe = Ph (2) PCH (2) CH (2) PPh (2), 1,2-bis (diphenylphosphino) ethane) (10) has been synthesized.
1(0,0,0,1) Details
11749622 Xiao L, Kitzler R, Weissensteiner W: O-Methylephedrine: a versatile and highly efficient ortho-directing group. J Org Chem. 2001 Dec 28;66(26):8912-9.


As an application, ferrocenyl diphosphines possessing a planar (R (p))-ferrocene configuration only [1,2-(PPh (2)) FcCH (2) PR (2), R = Cy, Ph, [3,5-(CF (3))(2) Ph]] were synthesized in three steps from O-methylephedrine and N-ferrocenylmethyl-N,N,N-trimethylammonium iodide in up to 77% overall yield.
1(0,0,0,1) Details