| 20014798 |
Mitoraj MP, Michalak A: Sigma-donor and pi-acceptor properties of phosphorus ligands: an insight from the natural orbitals for chemical valence. Inorg Chem. 2010 Jan 18;49(2):578-82.
The bonding between phosphorus ligands X = PCl (3), PF (3), P (OCH (3))(3), PH (3), PH (2) CH (3), PH (CH (3))(2), P (CH (3))(3) and the metal-containing fragments [Ni (CO)(3)], [Mo (CO)(5)], and [Fe (CO)(4)] have been studied by Natural Orbitals for Chemical Valence (NOCV). |
2(0,0,0,2) |
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| 11666212 |
Wong CY, McDonald R, Cavell RG: Hexacoordinate Phosphorus. 7. Inorg Chem. 1996 Jan 17;35(2):325-334.
The silylated form of the related thiobis (phenol), 2,2'-thiobis (4,6-tert-butylphenol), reacted similarly with pentavalent halides to form the six-coordinate complex [{2-O-3,5-((t) Bu)(2) C (6) H (2)}(2) S] PCl (3) which was also verified by a crystal structure. |
2(0,0,0,2) |
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