Protein Information

Name HL 3
Synonyms Cytoplasmic dynein heavy chain 1; p22; DHC 1; DHC1; DHC1a; DNCH 1; DNCH1; DNCHC 1…

Compound Information

Name OCH
CAS 2,3,4,4,5,5,6,6-octachloro-2-cyclohexen-1-one

Reference List

PubMed Abstract RScore(About this table)
11825074 Belle C, Beguin C, Gautier-Luneau I, Hamman S, Philouze C, Pierre JL, Thomas F, Torelli S, Saint-Aman E, Bonin M: Dicopper (II) complexes of H-BPMP-type ligands: pH-induced changes of redox, spectroscopic ((19) F NMR studies of fluorinated complexes), structural properties, and catecholase activities. Inorg Chem. 2002 Feb 11;41(3):479-91.


Substitution of the methyl group from the H-BPMP (HL (CH) 3) ligand (2,6-bis [(bis (2-pyridylmethyl) amino) methyl]-4-methylphenol) by electron withdrawing (F or CF (3)) or electron donating (OCH (3)) groups afforded a series of dinucleating ligand (HL (OCH) 3, HL (F), HL (CF) 3), allowing one to understand the changes in the properties of the corresponding dicopper complexes.
2(0,0,0,2) Details
18314953 Lopez-Torres E, Abram U: Rhenium complexes with triazine derivatives formed from semicarbazones and thiosemicarbazones. Inorg Chem. 2008 Apr 7;47(7):2890-6. Epub 2008 Mar 4.


This contrasts the behavior of the analogous thione HL (3), which preferably coordinates to nitridorhenium (V) centers via the sulfur atom.
2(0,0,0,2) Details
16172647 Ni Dhubhghaill OM, Lennon J, Drew MG: Palladium (II) and platinum (II) complexes with tridentate iminophosphine ligands; synthesis and structural studies. Dalton Trans. 2005 Oct 7;(19):3213-20. Epub 2005 Aug 30.


The previously synthesised Schiff-base ligands 2-(2-Ph (2) PC (6) H (4) N [double bond, length as m-dash] CH)-R'-C (6) H (3) OH (R'= 3-OCH (3), HL (1); 5-OCH (3), HL (2); 5-Br, HL (3); 5-Cl, HL (4)) were prepared by a faster, more efficient route involving a microwave assisted co-condensation of 2-(diphenylphosphino) aniline with the appropriate substituted salicylaldehyde.
1(0,0,0,1) Details
17142091 El-Dissouky A, Al-Awadi NA, Shauib NM, Abbas AB: Synthesis and spectroscopic studies on iron (III) complexes of 1-benzotriazol-1-yl-1-[(p-X-phenyl) hydrazono] propan-2-one. Spectrochim Acta A Mol Biomol Spectrosc. 2007 Jul;67(3-4):1072-9. Epub 2006 Oct 4.


The magnetic and spectral studies showed that [FeLCl (2)] are polymeric octahedral, [Fe (L (1))(3)].H (2) O is a low spin octahedral and (d (xz),d (yz))(4) (d (xy))(1) ground state, [FeL (3)].nH (2) O, L=anion of HL (4) or HL (5) and are octahedral with intermediate spin (S=32) with ground state (d (xy))(2)(d (xz),d (yz))(3) electronic configuration while for the anions of HL (2) and HL (3), they have (t (2g))(3)(e (g))(5) admixed with (d (xy))(2)(d (xz),d (yz))(3) configurations.
1(0,0,0,1) Details