Protein Information

Name Cl 2
Synonyms AMB11; MHC class I NK cell receptor; CD158E1; CD158E1/2; CD158E2; CL 11; CL 2; HLA BW4 specific inhibitory NK cell receptor…

Compound Information

Name OCH
CAS 2,3,4,4,5,5,6,6-octachloro-2-cyclohexen-1-one

Reference List

PubMed Abstract RScore(About this table)
12444797 Longlet JJ, Bodige SG, Watson WH, Neilson RH: Synthesis, structure, and reactivity of some N-phosphorylphosphoranimines. Inorg Chem. 2002 Dec 2;41(24):6507-13.


Thus, treatment of the N-silylphosphoranimines, Me (3) SiN=P (Me)(R) X (R = Me, Ph; X = OCH (2) CF (3) and R = Me, X = OPh), with phosphoryl chlorides, RP (=O) Cl (2) (R' = Cl, Me, Ph), readily afforded the corresponding N-phosphoryl derivatives, R'P (=O)(Cl)-N=P (Me)(R) X, in high yields.
2(0,0,0,2) Details
19470521 Nishina Y, Sato K, Tamaoki H, Setoyama C, Miura R, Shiga K: FT-IR spectroscopic studies on the molecular mechanism for substrate specificity/activation of medium-chain acyl-CoA dehydrogenase. J Biochem. 2009 Sep;146(3):351-7. Epub 2009 May 26.


The interactions of acyl-CoA with medium-chain acyl-CoA dehydrogenases (MCADs) reconstituted with artificial FADs-i.e. 8-CN-, 7,8-Cl (2)-, 8-Cl-, 8-OCH (3)- and 8-NH (2)-FAD-were investigated by UV-visible absorption and FT-IR measurements.
1(0,0,0,1) Details
11666801 Richter-Addo GB, Hodge SJ, Yi GB, Khan MA, Ma T, Van Caemelbecke E, Guo N, Kadish KM: Synthesis, Characterization, and Spectroelectrochemistry of Cobalt Porphyrins Containing Axially Bound Nitric Oxide. Inorg Chem. 1996 Oct 23;35(22):6530-6538.


They are diamagnetic and display nu (NO) bands in CH (2) Cl (2) between 1681 and 1695 cm (-)(1).
2(0,0,0,2) Details
14514302 Triller MU, Pursche D, Hsieh WY, Pecoraro VL, Rompel A, Krebs B: Catalytic oxidation of 3,5-Di-tert-butylcatechol by a series of mononuclear manganese complexes: synthesis, structure, and kinetic investigation. Inorg Chem. 2003 Oct 6;42(20):6274-83.


Complexes 1-4 are structurally related to the proposed active site of the manganese-dependent extradiol-cleaving catechol dioxygenase exhibiting an N (4) O (2) donor set (1 and 2) or N (4) Cl (2) donor set (3 and 4).
1(0,0,0,1) Details
19350590 Pettirossi S, Bellachioma G, Ciancaleoni G, Zuccaccia C, Zuccaccia D, Macchioni A: Diffusion and NOE NMR studies on multicationic DAB-organoruthenium dendrimers: size-dependent noncovalent self-assembly to megamers and ion pairing. Chemistry. 2009;15(21):5337-47.


Diffusion NMR experiments on RuPF (6)-Dabn dendrimers in CD (2) Cl (2) at different concentrations revealed a process of supramolecular assembly of dendrimers to megamers that is strongly favored for the highest generations.
1(0,0,0,1) Details
11666327 Wang D, Angelici RJ: Effects of Cyclopentadienyl and Phosphine Ligands on the Basicities and Nucleophilicities of Cp'Ir (CO)(PR (3)) Complexes. Inorg Chem. 1996 Feb 28;35(5):1321-1331.


The nucleophilicities of the Cp'Ir (CO)(PR (3)) complexes were established from second-order rate constants (k) for their reactions with CH (3) I to give [Cp'Ir (CO)(PR (3))(CH (3))](+) I (-) in CD (2) Cl (2) at 25.0 degrees C.
1(0,0,0,1) Details
14989655 McNaughton RL, Helton ME, Cosper MM, Enemark JH, Kirk ML: Nature of the oxomolybdenum-thiolate pi-bond: implications for Mo-S bonding in sulfite oxidase and xanthine oxidase. Inorg Chem. 2004 Mar 8;43(5):1625-37.


The electronic structure of cis,trans-(L-N (2) S (2)) MoO (X) (where L-N (2) S (2) = N,N'-dimethyl-N,N'-bis (2-mercaptophenyl) ethylenediamine and X = Cl, SCH (2) C (6) H (5), SC (6) H (4)-OCH (3), or SC (6) H (4) CF (3)) has been probed by electronic absorption, magnetic circular dichroism, and resonance Raman spectroscopies to determine the nature of oxomolybdenum-thiolate bonding in complexes possessing three equatorial sulfur ligands.
1(0,0,0,1) Details
16257689 de Oliveira PR, Rittner R: 1,3-Diaxial steric effects and intramolecular hydrogen bonding in the conformational equilibria of new cis-1,3-disubstituted cyclohexanes using low temperature NMR spectra and theoretical calculations. Spectrochim Acta A Mol Biomol Spectrosc. 2005 Nov;62(1-3):30-7.


The conformational equilibria of 3-X-cyclohexanol [X=F (1), Cl (2), Br (3), I (4), Me (5), NMe (2) (6) and MeO (7)] and of 3-X-methoxycyclohexane [X=F (8), Cl (9), Br (10), I (11), Me (12), NMe (2) (13) and MeO (14)] cis isomers were determined from low temperature NMR spectra and PCMODEL calculated coupling constants.
1(0,0,0,1) Details
12456988 Besli S, Coles SJ, Davies DB, Hursthouse MB, Kilic A, Mayer TA, Shaw RA: Structural investigations of phosphorus-nitrogen compounds. 5. Acta Crystallogr B. 2002 Dec;58(Pt 6):1067-73. Epub 2002 Nov 28.


A systematic study of the products of nucleophilic substitution reactions of cis-ansa N (3) P (3) Ph (2)[O (CH (2) CH (2) O)(4)] Cl (2) (3) is reported.
1(0,0,0,1) Details
12079463 Li M, Bonnet D, Bill E, Neese F, Weyhermuller T, Blum N, Sellmann D, Wieghardt K: Tuning the electronic structure of octahedral iron complexes [FeL (X)] (L = 1-alkyl-4,7-bis (4-tert-butyl-2-mercaptobenzyl)-1,4,7-triazacyclononane, X = Cl, CH (3) O, CN, NO). Inorg Chem. 2002 Jul 1;41(13):3444-56.


Complexes [Zn (L (Pr))] (1), 4.CH (3) OH, 5.0.5toluene.CH (2) Cl (2), and 7.2.5CH (2) Cl (2) have been structurally characterized by low-temperature (100 K) X-ray crystallography.
1(0,0,0,1) Details
11670560 Isovitsch RA, Beadle AS, Fronczek FR, Maverick AW: Electronic Absorption Spectra and Phosphorescence of Oxygen-Containing Molybdenum (IV) Complexes. Inorg Chem. 1998 Aug 24;37(17):4258-4264.


Phosphorescence (lambda (max,em) 850-960 nm) occurs in the solid state for all three compounds at both room temperature and 77 K, and for [MoOCl (CN-t-Bu)(4)](+) in CH (2) Cl (2) at room temperature.
1(0,0,0,1) Details
12590539 Jensen MP, Lange SJ, Mehn MP, Que EL, Que L Jr: Biomimetic aryl hydroxylation derived from alkyl hydroperoxide at a nonheme iron center. J Am Chem Soc. 2003 Feb 26;125(8):2113-28.


Transient intermediates were observed at low temperature by UV-visible spectroscopy, and these were characterized as iron (III) alkylperoxo complexes by resonance Raman and EPR spectroscopies for L (1) and L (8). [(L (1)) Fe (II)(OTf)(2)] gave rise to a mixture of high-spin (S = 5/2) and low-spin (S = 1/2) Fe (III)-OOR isomers in acetonitrile, whereas both [(L (1)) Fe (OTf)(2)] in CH (2) Cl (2) and [(L (8)) Fe (OTf)(2)](2) in acetonitrile afforded only high-spin intermediates.
1(0,0,0,1) Details
15606213 Tisato F, Refosco F, Porchia M, Bolzati C, Bandoli G, Dolmella A, Duatti A, Boschi A, Jung CM, Pietzsch HJ, Kraus W: The crucial role of the diphosphine heteroatom X in the stereochemistry and stabilization of the substitution-inert [M (N)(PXP)] 2+ metal fragments (M = Tc, Re; PXP = diphosphine ligand). Inorg Chem. 2004 Dec 27;43(26):8617-25.


Thus, by mixing PXP ligands with labile [Re (N) Cl (4)](-) and Tc (N) Cl (2)(PPh (3))(2) nitrido precursors in CH (2) Cl (2)/MeOH mixtures, a series of neutral M (N) Cl (2)(PXP) complexes (M = Tc, 1-5; M = Re, 8, 9) was collected.
1(0,0,0,1) Details
11735489 Bereau VM, Khan SI, Abu-Omar MM: Synthesis of enantiopure oxorhenium (V) and arylimidorhenium (V) "3 + 2" Schiff base complexes. Inorg Chem. 2001 Dec 17;40(26):6767-73.


Crystal data: (3) C (32) H (27) N (2) O (5) Re.CH (2) Cl (2), orthorhombic, P2 (1) 2 (1) 2 (1), a = 9.5599 (16) A, b = 9.9579 (16) A, c = 31.712 (5) A, V = 3018.9 (9) A (3), T = 100 (2) K, Z = 4. (5) C (40) H (38) N (3) O (5) Re, monoclinic, P2 (1), a = 9.286 (3) A, b = 18.759 (6) A, c = 9.957 (3) A, beta = 102.817 (6) degrees, V = 1691.3 (10) A (3), T = 100 (2) K, Z = 2.
1(0,0,0,1) Details
19693757 Taher D, Thibault ME, Di Mondo D, Jennings M, Schlaf M: Acid-, water- and high-temperature-stable ruthenium complexes for the total catalytic deoxygenation of glycerol to propane. Chemistry. 2009 Oct 5;15(39):10132-43.


The ruthenium aqua complexes [Ru (H (2) O)(2)(bipy)(2)](OTf)(2), [cis-Ru (6,6'-Cl (2)-bipy)(2)(OH (2))(2)](OTf)(2), [Ru (H (2) O)(2)(phen)(2)](OTf)(2), [Ru (H (2) O)(3)(2,2':6',2''-terpy)](OTf)(2) and [Ru (H (2) O)(3)(Phterpy)](OTf)(2) (bipy = 2,2'-bipyridine; OTf (-) = triflate; phen = phenanthroline; terpy = terpyridine; Phterpy = 4'-phenyl-2,2':6',2''-terpyridine) are water- and acid-stable catalysts for the hydrogenation of aldehydes and ketones in sulfolane solution.
1(0,0,0,1) Details
15137785 Lee D, Donkers RL, Wang G, Harper AS, Murray RW: Electrochemistry and optical absorbance and luminescence of molecule-like Au38 nanoparticles. J Am Chem Soc. 2004 May 19;126(19):6193-9.


Voltammetry of the Au (38) nanoparticles in CH (2) Cl (2) reveals a 1.62 V energy gap between the first one-electron oxidation and the first reduction.
1(0,0,0,1) Details
19826731 Rix FC, Rachita MJ, Wagner MI, Brookhart M, Milani B, Barborak JC: Palladium (II)-catalyzed copolymerization of styrenes with carbon monoxide: mechanism of chain propagation and chain transfer. Dalton Trans. 2009 Nov 7;(41):8977-92. Epub 2009 Sep 3.


The copolymerization in CH (2) Cl (2) or chlorobenzene has been found to be first order in styrene and inverse first order in CO concentrations.
1(0,0,0,1) Details
16913692 Tsuzuki S, Honda K, Uchimaru T, Mikami M, Fujii A: Magnitude and directionality of the interaction energy of the aliphatic CH/pi interaction: significant difference from hydrogen bond. J Phys Chem A. 2006 Aug 24;110(33):10163-8.


The estimated interaction energies of the benzene complexes with CH (4), CH (3) CH (3), CH (2) CH (2), CHCH, CH (3) NH (2), CH (3) OH, CH (3) OCH (3), CH (3) F, CH (3) Cl, CH (3) ClNH (2), CH (3) ClOH, CH (2) Cl (2), CH (2) FCl, CH (2) F (2), CHCl (3), and CH (3) F (3) are -1.45, -1.82, -2.06, -2.83, -1.94, -1.98, -2.06, -2.31, -2.99, -3.57, -3.71, -4.54, -3.88, -3.22, -5.64, and -4.18 kcal/mol, respectively.
1(0,0,0,1) Details
19513491 Antonioli B, Buchner B, Clegg JK, Gloe K, Gloe K, Gotzke L, Heine A, Jager A, Jolliffe KA, Kataeva O, Kataev V, Klingeler R, Krause T, Lindoy LF, Popa A, Seichter W, Wenzel M: Interaction of an extended series of N-substituted di (2-picolyl) amine derivatives with copper (II). Dalton Trans. 2009 Jun 28;(24):4795-805. Epub 2009 Apr 29.


The solid complexes [Cu ()(micro-Cl)](2)(PF (6))(2), [Cu ()(micro-Cl)](2)(PF (6))(2).0.5CH (2) Cl (2), Cu ()(ClO (4))(2), Cu ()(2)(ClO (4))(2), [Cu ()(ClO (4))(2)(H (2) O)].0.5H (2) O, Cu (2)()(ClO (4))(4), [Cu (2)()(Cl)(4)] and [Cu (2)(+H)(micro-OCH (3))(2)(H (2) O)](ClO (4))(3).C (4) H (10) O were isolated and X-ray structures of [Cu ()(micro-Cl)](2)(PF (6))(2), [Cu ()(micro-Cl)](2)(PF (6))(2).0.5CH (2) Cl (2,) [Cu ()(2)(ClO (4))(2)(H (2) O)].0.5H (2) O, [Cu (2)() Cl (4)] and [Cu (2)(+H)(micro-OCH (3))(2)(H (2) O)](ClO (4))(3).C (4) H (10) O were obtained.
1(0,0,0,1) Details
18200585 Kumar NN, Swamy KC: Single diastereomers of unsymmetrical tris-spirocyclic cyclotriphosphazenes based on 1,1'-bi-2-naphthol--synthesis and structures. Chirality. 2008 Jun;20(6):781-9.


Specifically, the chiral compounds (-) N (3) P (3)[1,1'-O (2)(C (10) H (6))(2)](O-2,2'C (6) H (4)-C (6) H (4) O) Cl (2) [(-)-4] and (-) N (3) P (3)[1,1'-O (2)(C (10) H (6))(2)](OCH (2) CH (2) NMe)(2) [(-)-5] are prepared by starting with the chiral mono-spiro compound (-) N (3) P (3)[1,1'-O (2)(C (10) H (6))(2)] Cl (4) [(-)-3].
1(0,0,0,1) Details
17033704 Barnes NA, Godfrey SM, Halton RT, Mushtaq I, Pritchard RG: The reaction of tertiary phosphines with (Ph2Se2I2) 2--the influence of steric and electronic effects. Dalton Trans. 2006 Oct 28;(40):4795-804. Epub 2006 Aug 3.


The crystal structures of (m-CH (3) C (6) H (4))(3) PSe (Ph) I, 2, (o-CH (3) C (6) H (4))(3) PI (2), 3, [(o-OCH (3) C (6) H (4))(3) PSePh] I.CH (2) Cl (2), 4, [(o-SCH (3) C (6) H (4))(3) PSePh] I (3), 5b, two pseudo-polymorphs of Ph (2) MePSe (Ph) I, 6a/6b, and [Me (3) PSe (Ph) I](2).CH (2) Cl (2), 8, are reported.
1(0,0,0,1) Details
11498605 Nie Y, Hu CH, Li X, Yong W, Dou JM, Sun J, Jin RS, Zheng PJ: Three monoalkoxy-substituted nido-platinaboranes: [(PPh3) 2PtB10H11-8-(OCH3)], [(PPh3) 2PtB10H11-8-[OCH-(CH3) 2]] and [(PPh3) 2PtB10H10-9-[OCH (CH3) 2]]. Acta Crystallogr C. 2001 Aug;57(Pt 8):897-9. Epub 2001 Aug 9.

Each of the title compounds, 8-methoxy-7,7-bis (triphenylphosphine-P)-8,9:10,11-di-muH-7-platina-nido-un decaborane dichloromethane hemisolvate, [Pt (CH (14) B (10) O)(C (18) H (15) P)(2)].0.5CH (2) Cl (2), (I), 8-isopropoxy-7,7-bis (triphenylphosphine-P)-8,9:10,11-di-muH-7-platina-nido -undecaborane dichloromethane solvate, [Pt (C (3) H (18) B (10) O)(C (18) H (15) P)(2)].CH (2) Cl (2), (II), and 9-isopropoxy-7,7-bis (triphenylphosphine-P)-8,9:10,11-di-muH-7-platina-nido -undecaborane dichloromethane solvate, [Pt (C (3) H (18) B (10) O)(C (18) H (15) P)(2)].CH (2) Cl (2), (III), has an 11-vertex nido polyhedral skeleton, with the 7-platinum centre ligating to two exo-polyhedral PPh (3) groups and an alkoxy-substituted polyhedral borane ligand.
1(0,0,0,1) Details
20148217 Ghosh M, Weyhermuller T, Wieghardt K: Electronic structure of the members of the electron transfer series [NiL](z) (z = 3+, 2+, 1+, 0) and [NiL (X)](n) (X = Cl, CO, P (OCH (3))(3)) species containing a tetradentate, redox-noninnocent, Schiff base macrocyclic ligand L: an experimental and density functional theoretical study. Dalton Trans. 2010 Feb 28;39(8):1996-2007. Epub 2010 Jan 14.


The electrochemistry of [Ni (II)(L (Ox))](PF (6))(2) in the presence of hard chloride anions shows the presence of trans-[Ni (III)(L (Ox)) Cl (2)](+), the EPR spectrum of which has been recorded and calculated, and of trans-[Ni (II)(L (Ox)) Cl (2)](0) (S = 1).
1(0,0,0,1) Details
12716213 Briand GG, Burford N, Eelman MD, Cameron TS, Robertson KN: Synthesis and structures of the first bismuth-ester complexes using heterobifunctional thiolate anchored ligands and mass spectrometric identification of ligand-bridged derivatives. Inorg Chem. 2003 May 5;42(9):3136-41.


The first systematic series of bismuth complexes involving ester donors, Bi (SCH (2) C (O) OCH (2) CH (3)) Cl (2), Bi (SCH (2) C (O) OCH (3))(2) Cl, and Bi (SCH (2) COOCH (3))(3), has been isolated and characterized by spectroscopic (IR, Raman) and X-ray crystallographic data.
1(0,0,0,1) Details
19888732 Jenkin ME, Hurley MD, Wallington TJ: Investigation of the radical product channel of the CH (3) OCH (2) O (2) + HO (2) reaction in the gas phase. J Phys Chem A. 2010 Jan 14;114(1):408-16.


The reaction of CH (3) OCH (2) O (2) with HO (2) has been investigated at 296 K and 700 Torr using long path FTIR spectroscopy, during photolysis of Cl (2)/CH (3) OCH (3)/CH (3) OH/air mixtures.
1(0,0,0,1) Details
19417941 Postigo L, Sanchez-Nieves J, Royo P, Mosquera ME: Dinuclear dialkoxo-bridged cyclopentadienylsiloxo titanium complexes. . Dalton Trans. 2009 May 21;(19):3756-65. Epub 2009 Mar 18.


One benzyl group of complexes was abstracted with E (C (6) F (5))(3) (E = B, Al) to give the monoionic compounds [Ti (TiBz)(mu-O (2) L)(mu-{(eta (5)-C (5) Me (4) SiMeO)(2)(mu-O)})][BzE (C (6) F (5))( 3)] (O (2) L = 1,2-O (2) C (2) H (4), E = B , Al ; O (2) L = 1,2-O (2) C (6) H (4), E = B ), although was unstable in CD (2) Cl (2) evolving to a mixture of compounds where [(TiBz)(2)(mu-Cl)(mu-{(eta (5)-C (5) Me (4) SiMeO)(2)(mu-O)})][BzAl (C (6) F (5))(3 )] () was identified, and compound was also unstable at ambient temperature.
1(0,0,0,1) Details
11666871 Breeze SR, Wang S, Greedan JE, Raju NP: Copper and Bismuth Complexes Containing Dipyridyl gem-Diolato Ligands: Bi (III)(2)[(2-Py)(2) CO (OH)](2)(O (2) CCF (3))(4)(THF)(2), Cu (II)[(2-Py)(2) CO (OH)](2)(HO (2) CCH (3))(2), and Cu (II)(4)[(2-Py)(2) CO (OH)](2)(O (2) CCH (3))(6)(H (2) O)(2), a Ferromagnetically Coupled Tetranuclear Copper (II) Chain. Inorg Chem. 1996 Nov 20;35(24):6944-6951.


Crystal data: 1, C (38) H (34) N (4) O (14) F (12) Bi (2), triclinic P&onemacr;, a = 11.764 (3) A, b = 11.949 (3) A, c = 9.737 (1) A, alpha =101.36 (2) degrees, beta = 105.64 (2) degrees, gamma = 63.79 (2) degrees, Z = 1; 2, C (26) H (26) N (4) O (8) Cu/CH (2) Cl (2), monoclinic C2/c, a = 25.51 (3) A, b = 7.861 (7) A, c = 16.24 (2) A, beta = 113.08 (9) degrees, Z = 4; 3, C (34) H (40) N (4) O (18) Cu (4)/CH (2) Cl (2), triclinic P&onemacr;, a = 10.494 (2) A, b = 13.885 (2) A, c = 7.900 (4) A, alpha =106.52 (2) degrees, beta = 90.85 (3) degrees, gamma = 94.12 (1) degrees, Z = 1.
1(0,0,0,1) Details
16241142 Chandrasekaran P, Mague JT, Balakrishna MS: Cyclodiphosphazanes with hemilabile ponytails: synthesis, transition metal chemistry (Ru (II), Rh (I), Pd (II), Pt (II)), and crystal and molecular structures of mononuclear (Pd (II), Rh (I)) and bi- and tetranuclear rhodium (I) complexes. Inorg Chem. 2005 Oct 31;44(22):7925-32.


The reaction of 2 with [M (COD) Cl (2)] afforded cis-[MCl (2)(2)(2)] derivatives (M = Pd (6), Pt (7)), whereas, with [Pd (NCPh)(2) Cl (2)], trans-[MCl (2)(2)(2)] (8) was obtained.
1(0,0,0,1) Details
12203319 Cameron TS, Decken A, Dionne I, Fang M, Krossing I, Passmore J: Approaching the gas-phase structures of [AgS8]+ and [AgS16]+ in the solid state. Chemistry. 2002 Aug 2;8(15):3386-401.


Upon treating elemental sulfur with [AgSbF (6)], [AgAl (hfip)(4)], [AgAl (pftb)(4)] (hfip=OCH (CF (3))(2), pftb =OC (CF (3))(3)) the compounds [Ag (S (8))(2)][SbF (6)] (1), [AgS (8)][Al (hfip)(4)] (2), and [Ag (S (8))(2)](+)[[Al (pftb)(4)](-) (3) formed in SO (2) (1), CS (2) (2), or CH (2) Cl (2) (3).
1(0,0,0,1) Details
11670055 Belanger S, Beauchamp AL: Oxo Ligand Reactivity in the [ReO (2) L (4)](+) Complex of 1-Methylimidazole. Inorg Chem. 1997 Aug 13;36(17):3640-3647.


The oxo group of [ReO (2)(1-MeIm)(4)](+) can be methylated with excess methyl trifluoromethanesulfonate in CH (2) Cl (2) under mild conditions, leading to [ReO (OCH (3))(1-MeIm)(4)](CF (3) SO (3))(2), which is converted to the B (C (6) H (5))(4)(-) and PF (6)(-) salts.
1(0,0,0,1) Details
19526993 Sobota P, Drag-Jarzabek A, John L, Utko J, Jerzykiewicz LB, Duczmal M: Cyclopentadienyl/Alkoxo Ligand Exchange in Group 4 Metallocenes: A Convenient Route to Heterometallic Species. Inorg Chem. 2009 Jun 15.


In the reactions presented, a series of compounds, [Ca (4) Ti (2)(mu (6)-O)(mu (3),eta (2)-L)(8)(eta-L)(2) Cl (4)] (1), [Sr (4) Hf (2)(mu (6)-O)(mu (3),eta (2)-L)(8)(eta-L)(2)(eta-LH)(4) Cl (4)] (2), [Ca (4) Zr (2)(mu (6)-O)(mu-Cl)(4)(mu,eta (2)-L)(8) Cl (2)] (3), [Sr (4) Ti (2)(mu (6)-O)(mu (3),eta (2)-L)(8)(eta-L)(2)(eta-LH)(2) Cl (4)] (4), [Ca (4) Zr (2) Cp (2)(mu (4)-Cl)(mu-Cl)(3)(mu (3),eta (2)-L)(4)(mu,eta (2)-L)(4) Cl ( 2)] (5), [CaTiCl (2)(mu,eta (2)-L')(3)(eta-L'H)(3)][L'] (6), [Ca (2) Ti (mu,eta (2)-L')(6) Cl (2)] (7), [Mn (4) Ti (4)(mu-Cl)(2)(mu (3),eta (2)-L)(2)(mu,eta (2)-L)(10) Cl (6)] (8), and [Mn (10) Zr (10)(mu (4)-O)(10)(mu (3)-O)(4)(mu (3),eta (2)-L)(2)(mu,eta (2)-L)(16) (mu,eta-L)(4)(eta-L)(2) Cl (8)] (9), were obtained in good yield.
1(0,0,0,1) Details
16143400 Malon M, Travnicek Z, Marek R, Strnad M: Synthesis, spectral study and cytotoxicity of platinum (II) complexes with 2,9-disubstituted-6-benzylaminopurines. J Inorg Biochem. 2005 Nov;99(11):2127-38. Epub 2005 Sep 6.

The complexes have the following composition: cis-[Pt (Boh)(2) Cl (2)] (1), cis-[Pt (Oc)(2) Cl (2)] (2), cis-[Pt (Ros)(2) Cl (2)] (3), cis-[Pt (i-PrOc)(2) Cl (2)] (4), cis-[Pt (BohH (+))(2) Cl (2)] Cl (2) (5), cis-[Pt (OcH (+))(2) Cl (2)] Cl (2) (6), cis-[Pt (RosH (+))(2) Cl (2)] Cl (2) (7) and cis-[Pt (i-PrOcH (+))(2) Cl (2)] Cl (2) (8), where Boh=2-(3-hydroxypropylamino)-6-benzylamino-9-isopropylpurine, Oc=2-(2-hydroxyethylamino)-6-benzylamino-9-methylpurine, Ros=2-(R)-(1-ethyl-2-hydroxyethylamino)-6-benzylamino-9-isopropylpurine and i-PrOc=2-(2-hydroxyethylamino)-6-benzylamino-9-isopropylpurine.
31(0,1,1,1) Details
14606825 Bradley PM, Smith LT, Eglin JL, Turro C: Direct observation of the luminescence from the (3) deltadelta excited state of Re (2) Cl (2)(p-OCH (3) form)(4). Inorg Chem. 2003 Nov 17;42(23):7360-2.

Here we report the luminescence of Re (2) Cl (2)(p-OCH (3) form)(4) [p-OCH (3) form = (p-CH (3) OC (6) H (4)) NCHN (p-CH (3) OC (6) H (4))(-)] observed upon 400-460 nm excitation with maxima at 820 nm (CH (2) Cl (2), tau = 1.4 micros) and 825 nm (CH (3) CN, tau = 1.3 micros) at 298 K.
6(0,0,1,1) Details
10864758 Muthiah C, Kumar KP, Mani CA, Kumara Swamy KC: Chlorophosphonates: inexpensive precursors for stereodefined chloro-substituted olefins and unsymmetrical disubstituted acetylenes. J Org Chem. 2000 Jun 16;65(12):3733-7.

The structures of the phosphonates (OCH (2) CMe (2) CH (2) O) P (O) CH (2)(C (4) H (2) ClO) (4) and (OCH (2) CMe (2) CH (2) O) P (O)(CH=CHCH (Cl) Ph (7) have been determined; in addition, the stereochemistry of (5-chlorofurfuryl) CH=CH (4-ClC (6) H (4)) (13b) and 2, 4-Cl (2) C (6) H (3)-CH=CH-CH=C (Ph) Cl (14a) is unambiguously proved by the X-ray structure determination.
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11666239 Lindner E, Schreiber R, Schneller T, Wegner P, Mayer HA, Gopel W, Ziegler C: Synthesis of Polysiloxane-Bound (Ether-phosphine) palladium Complexes. Inorg Chem. 1996 Jan 17;35(2):514-525.


The reaction of two equiv of the monomeric ether-phosphine O,P ligand (MeO)(3) Si (CH (2))(3)(Ph) PCH (2)-Do [1a (T (0)()), 1b (T (0)())] {Do = CH (2) OCH (3) [1a (T (0)())], CHCH (2) CH (2) CH (2) O [1b (T (0)())]} with PdCl (2)(COD) yields the monomeric palladium (II) complexes Cl (2) Pd (P approximately O)(2) [2a (T (0)())(2)(), 2b (T (0)())(2)()].
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19228051 Kaiser EW, Wallington TJ, Hurley MD: Products and mechanism of the reaction of Cl with butanone in N2/O2 diluent at 297-526 K. J Phys Chem A. 2009 Mar 19;113(11):2424-37.


The products, kinetics, and mechanism of the reaction Cl + butanone have been measured by UV irradiation of Cl (2)/butanone/N (2) (O (2)) mixtures using either GC or FTIR analysis.
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