| 20165760 |
Gonzalez J, Torrent-Sucarrat M, Anglada JM: The reactions of SO3 with HO2 radical and H2O..HO2 radical complex. Phys Chem Chem Phys. 2010 Mar 7;12(9):2116-25. Epub 2010 Jan 14.
The reaction with the H (2) O...HO (2) radical complex can give two different products, namely (a) HSO (5) + H (2) O, which has a binding energy that is computed to be 4.76 kcal mol (-1) more stable than the SO (3) + H (2) O...HO (2) reactants (Delta (E + ZPE) at 0K) and an estimated branching ratio of about 34% at 298K and (b) sulfuric acid and the hydroperoxyl radical, which is computed to be 10.51 kcal mol (-1) below the energy of the reactants (Delta (E + ZPE) at 0K), with an estimated branching ratio of about 66% at 298K. |
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