Name | Cl 2 |
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Synonyms | AMB11; MHC class I NK cell receptor; CD158E1; CD158E1/2; CD158E2; CL 11; CL 2; HLA BW4 specific inhibitory NK cell receptor… |
Name | cyanamide |
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CAS | cyanamide |
PubMed | Abstract | RScore(About this table) | |
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18813372 | Tyan MR, Bokach NA, Wang MJ, Haukka M, Kuznetsov ML, Kukushkin VY: Facile cyanamide- coupling mediated by cis- and trans-[PtIIL2] centers and giving metal-bound guanidines. Dalton Trans. 2008 Oct 14;(38):5178-88. Epub 2008 Aug 11. Diffusion of into CH (2) Cl (2) solutions of the dialkylcyanamide complexes cis- or trans-[PtCl (2)(RCN)(2)] (R = NMe (2), NEt (2), NC (5) H (10)) at 20-25 degrees C leads to metal-mediated cyanamide- coupling to furnish, depending on reaction time, one or another type of novel bisguanidine compound, i.e. the molecular cis- or trans-[PtCl (2){NH=C (NH (2)) R}(2)] (cis- and trans-) and the cationic cis- or trans-[Pt (NH (3))(2){NH=C (NH (2)) R}(2)](Cl)(2) (cis- and trans-) complexes. |
33(0,1,1,3) | Details |
11300809 | Ferreira CM, Guedes da Silva MF, Frausto da Silva JJ, Pombeiro AJ, Kukushkin VY, Michelin RA: Azametallacycles from Ag (I)- or Cu (II)-promoted coupling reactions of dialkylcyanamides with oximes at Pt (II). Inorg Chem. 2001 Mar 12;40(6):1134-42. The dialkylcyanamide complexes cis-[PtCl (NCNR (2))(PPh (3))(2)][BF (4)] 1 and cis-[Pt (NCNR (2))(2)(PPh (3))(2)][BF (4)](2) 2 (R = Me or Et) have been prepared by treatment of a CH (2) Cl (2) solution of cis-[PtCl (2)(PPh (3))(2)] with the appropriate dialkylcyanamide and one or two equivalents of Ag [BF (4)], respectively. In contrast, in the organonitrile complexes cis-[Pt (NCR)(2)(PPh (3))(2)][BF (4)](2) 5 (R = C (6) H (4) OMe-4 or Et), obtained in a similar way as 2 (but by using NCR instead of the cyanamide), the ligating NCR is not activated by the Lewis acid and does not couple with the oximes. |
2(0,0,0,2) | Details |