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Brask JK, Dura-Vila V, Diaconescu PL, Cummins CC: Vanadium nitride functionalization and denitrogenation by carbon disulfide and dioxide. Chem Commun. 2002 Apr 21;(8):902-3.
A dramatic difference in behavior is observed for the dithiocarbamate and carbamate complexes [Ar (But) N] 3V (NCE2) Na (THF) 2 (E = S or O, respectively), prepared from the corresponding nitride species ([Ar (But) N] 3V identical to NNa) 2 by way of a nucleophilic addition reaction involving carbon disulfide or dioxide, and is rationalized with the aid of DFT calculations. |
31(0,1,1,1) |
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