| 20013762 |
Osswald T, Ruegger H, Mezzetti A: Secondary interactions or ligand scrambling? Subtle steric effects govern the iridium (I) coordination chemistry of phosphoramidite ligands. Chemistry. 2010 Jan 25;16(4):1388-97.
Further studies with the unlike ligand (aS,R,R)-(1,1'-binaphthalene)-2,2'-diyl bis{[1-(1-naphthalene-1-yl) ethyl] phosphoramidite} (1 b) showed a yet different coordination mode, that is, the eta (4)-arene-metal interaction in (aS,R,R)-[Ir (cod)(1,2,3,4-eta-1 b,kappaP)](+) (3 b). |
82(1,1,1,2) |
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