Protein Information

Name Cl 2
Synonyms AMB11; MHC class I NK cell receptor; CD158E1; CD158E1/2; CD158E2; CL 11; CL 2; HLA BW4 specific inhibitory NK cell receptor…

Compound Information

Name naphthalene
CAS naphthalene

Reference List

PubMed Abstract RScore(About this table)
17368086 Zayed MA, Hawash MF, Fahmey MA, El-Habeeb AA: Structure investigation of sertraline drug and its iodine product using mass spectrometry, thermal analyses and MO-calculations. Spectrochim Acta A Mol Biomol Spectrosc. 2007 Nov;68(3):970-8. Epub 2007 Jan 20.

In thermal analyses (TA) the initial rupture in sertraline is due to the loss of C (6) H (3) Cl (2) followed by the loss of CH (3)-NH forming tetraline molecule which thermally decomposed to give C (4) H (8), C (6) H (6) or the loss of H (2) forming naphthalene molecule which thermally sublimated.
32(0,1,1,2) Details
20349936 Londesborough MG, Bould J, Base T, Hnyk D, Bakardjiev M, Holub J, Cisarova I, Kennedy JD: An Experimental Solution to the "Missing Hydrogens" Question Surrounding the Macropolyhedral 19-Vertex Boron Hydride Monoanion [B (19) H (22)](-), a Simplification of Its Synthesis, and Its Use As an Intermediate in the First Example of syn-B (18) H (22) to anti-B (18) H (22) Isomer Conversion. Inorg Chem. 2010 Mar 29.

The macropolyhedral [B (19) H (22)](-) monoanion 1 and the dianion [B (19) H (21)](2-) 2 are synthesized in consistent 86-92% yields by the reaction of [PSH](+)[syn-B (18) H (21)](-) with BH (3)(SMe (2)) in 1,2-Cl (2) C (2) H (4) at 72 degrees C. ['PS' is an abbreviation for 'Proton Sponge', 1,8-bis-(dimethylamino) naphthalene. 'PSH' is its protonated derivative.] The molecular structures of 1 and 2 were elucidated as their [PS{BH (2)}](+) and [PS{BH (2)}]()(2)(+) salts 1a and 2a by single-crystal X-ray diffraction studies, in which all atoms were located, and supported by mass spectrometric analyses together with calculations of the cluster molecular geometries (ab ignitio and/or DFT) and of (11) B chemical shifts based on GIAO-DFT shielding tensors.
31(0,1,1,1) Details
20148225 Holub J, Stibr B, Stepnicka P, Cisarova I: Synthesis and electrochemistry of some ferrocenyl substituted dicarba- and tricarbaborane compounds. Dalton Trans. 2010 Feb 28;39(8):2057-61. Epub 2010 Jan 13.

Heating of 2a at 400 degrees C led to the dehydrogenation and isolation of the orange 1-Fc-closo-1,10-C (2) B (8) H (9) (3) in almost quantitative yield, while treatment of 2a with t-BuNC and PS (proton sponge = 1,8-bis (dimethylamino) naphthalene) in CH (2) Cl (2) generated the neutral absolute tautomer 7-t-BuNH-8-Fc-7,8,9-C (3) B (8) H (10) (N4) (yield 50%), which could be converted quantitatively into the zwitterionic tautomer 7-t-BuNH (2)-8-Fc-7,8,9-C (3) B (8) H (9) (Z4) via dissolution in MeCN.
31(0,1,1,1) Details
16903734 Christoforou AM, Marzilli PA, Marzilli LG: The neglected Pt-N (sulfonamido) bond in Pt chemistry. Inorg Chem. 2006 Aug 21;45(17):6771-81.

Treatment of cis-Pt (Me2SO) 2Cl2 with DNSH-tren afforded [Pt (DNSH-tren) Cl] Cl and with DNSH-dienH, under increasingly more basic conditions, led to Pt (DNSH-dienH) Cl (2), Pt (DNSH-dien) Cl, and Pt (DNS-dien). (DNSH = 5-(dimethylamino) naphthalene-1-sulfonyl, linked via a sulfonamide group to tris (2-aminoethyl) amine (DNSH-tren) and diethylenetriamine (DNSH-dienH); the H's in DNSH-dienH designate protons sometimes lost upon Pt binding, i.e., sulfonamide NH for the dienH moiety and H8 for the DNSH moiety).
31(0,1,1,1) Details
18939820 Sazanovich IV, Alamiry MA, Best J, Bennett RD, Bouganov OV, Davies ES, Grivin VP, Meijer AJ, Plyusnin VF, Ronayne KL, Shelton AH, Tikhomirov SA, Towrie M, Weinstein JA: Excited state dynamics of a PtII diimine complex bearing a naphthalene-diimide electron acceptor. Inorg Chem. 2008 Nov 17;47(22):10432-45. Epub 2008 Oct 22.

A combination of picosecond time-resolved infrared spectroscopy, picosecond transient absorption spectroscopy, and nanosecond flash photolysis was used to elucidate the nature and dynamics of a manifold of the lowest excited states in Pt (phen-NDI) Cl 2 ( 1), where NDI = strongly electron accepting 1,4,5,8-naphthalene-diimide group. 1 is the first example of a Pt (II)-diimine-diimide dyad.
10(0,0,1,5) Details
18414757 Singh A, Anandhi U, Cinellu MA, Sharp PR: Diimine supported group 10 hydroxo, oxo, amido, and imido complexes. . Dalton Trans. 2008 May 7;(17):2314-27. Epub 2008 Mar 4.

Deprotonation of [L (2) Pt (mu-OH)](2)(2+) with 1,8-bis (dimethylamino) naphthalene, NaH, or KOH yields [(L (2) Pt)(2)(mu-OH)(mu-O)](+) as purple (Bian) or red (Bu (t)(2) bpy) solids.
Ni (Bu (t)(2) bpy) Cl (2) and [(Ph (3) PAu)(3)(mu-O)](+) in a 3 : 2 ratio yield red [Ni (3)(Bu (t)(2) bpy)(3)(mu-O)(2)](2+).
3(0,0,0,3) Details
19575350 Wright RJ, Lim C, Tilley TD: Diiron proton reduction catalysts possessing electron-rich and electron-poor naphthalene-1,8-dithiolate ligands. Chemistry. 2009 Aug 24;15(34):8518-25.

Cyclic voltammetry (CH (2) Cl (2)/nBu (4) PF (6)) revealed two one-electron reductions, at potentials more positive than those for the related [Fe (2)(CO)(6)(S (CH (2))(3) S)] (1), and one one-electron oxidation.
1(0,0,0,1) Details
19921777 Nippe M, Victor E, Berry JF: Oxidation chemistry of axially protected Mo (2) and W (2) quadruply bonded compounds. Inorg Chem. 2009 Dec 21;48(24):11889-95.

Reported is a facile, high-yielding one-pot synthesis of the quadruply bonded ditungsten (II,II) compound W (2)(dpa)(4) (1) (dpa = 2,2'-dipyridylamide), which was obtained from W (CO)(6) at high temperature in naphthalene.
The [W (2)(dpa)(3) Cl (2)](+) cation is better prepared by oxidation of 1 with SO (2) Cl (2).
1(0,0,0,1) Details
16851409 Alvaro M, Atienzar P, Corma A, Ferrer B, Garcia H, Navarro MT: Photochemical generation of electrons and holes in germanium-containing ITQ-17 zeolite. J Phys Chem B. 2005 Mar 3;109(8):3696-700.

The shorter lived transient (tau approximately 45 micros under nitrogen) has been assigned to trapped electrons due to the characteristic spectroscopic absorption (single band at 480 nm) and its quenching by typical electron scavengers such as N (2) O and CH (2) Cl (2).
The ability of Ge/ITQ-17 to generate photochemically electrons and holes has been confirmed by adsorbing naphthalene and propyl viologen sulfonate as electron donor and acceptor, respectively, and observing the generation of the corresponding radical ions.
1(0,0,0,1) Details
19722500 Giansante C, Mazzanti A, Baroncini M, Ceroni P, Venturi M, Klarner FG, Vogtle F: Tweezering the core of dendrimers: medium effect on the kinetic and thermodynamic properties. J Org Chem. 2009 Oct 2;74(19):7335-43.

Tweezer T comprises a naphthalene and four benzene components bridged by four methylene groups.
Medium effects on molecular recognition phenomena are discussed and provide insight into the conformation of dendrimers: change in solvent polarity from pure CH (2) Cl (2) to CH (2) Cl (2)/CH (3) CN mixtures and addition of tetrabutylammonium hexafluorophosphate (NBu (4) PF (6), up to 0.15 M), the supporting electrolyte used in the electrochemical measurements, have been investigated.
1(0,0,0,1) Details
20024986 Pietrzak M, Wehling JP, Kong S, Tolstoy PM, Shenderovich IG, Lopez C, Claramunt RM, Elguero J, Denisov GS, Limbach HH: Symmetrization of cationic hydrogen bridges of protonated sponges induced by solvent and counteranion interactions as revealed by NMR spectroscopy. Chemistry. 2010 Feb 1;16(5):1679-90.

The properties of the intramolecular hydrogen bonds of doubly (15) N-labeled protonated sponges of the 1,8-bis (dimethylamino) naphthalene (DMANH (+)) type have been studied as a function of the solvent, counteranion, and temperature using low-temperature NMR spectroscopy.
By contrast, studies using CD (2) Cl (2), [D (8)] toluene as well as the freon mixture CDF (3)/CDF (2) Cl, which is liquid down to 100 K, revealed an influence of temperature and of the counteranions.
1(0,0,0,1) Details