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Ledger J, Boomishankar R, Steiner A: Aqueous Chemistry of Chlorocyclophosphazenes: Phosphates {PO (2)}, Phosphamides {P (O) NHR}, and the first Phosphites {PHO} and Pyrophosphates {(PO)(2) O} of These Heterocycles. Inorg Chem. 2010 Mar 16.
Starting from geminal dichlorides (A) which are equipped with amino groups at the other two phosphorus atoms {(Z'(2) P)(2) N (3) PCl (2) (Z' = NHCy) and (Z''P)(2) N (3) PCl (2) (Z'' = {EtN (C (3) H (6)) NEt}), respectively}, phosphate (B), pyrophosphate (C), phosphamide (D), and phosphite (E) derivatives have been prepared. |
31(0,1,1,1) |
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